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| 3-ETHOXY-3-OXOPROPYLZINC BROMIDE Basic information |
| Product Name: | 3-ETHOXY-3-OXOPROPYLZINC BROMIDE | | Synonyms: | 3-ETHOXY-3-OXOPROPYLZINC BROMIDE;3-ETHOXY-3-OXOPROPYLZINC BROMIDE, 0.5MSO LUTION IN TETRAHYDROFURAN;3-ethoxy-3-oxopropylzinc bromide solution;2-(Ethoxycarbonyl)ethylzinc bromide, 0.5M in THF;2-(Ethoxycarbonyl)ethylzinc bromide;3-Ethoxy-3-oxopropylzinc bromide solution 0.5 in THF;(3-ethoxy-3-oxopropyl)zinc(II) broMide;3-Ethoxy-3-oxopropylzinc broMide solution 0.5 M in THF | | CAS: | 193065-68-8 | | MF: | C5H9BrO2Zn | | MW: | 246.41 | | EINECS: | | Product Categories: | Alkyl;Organozinc Halides;Reike and Organozinc Reagents | | Mol File: | 193065-68-8.mol |
| 3-ETHOXY-3-OXOPROPYLZINC BROMIDE Chemical Properties |
| density | 0.972 g/mL at 25 °C | | Fp | 1 °F | | storage temp. | 2-8°C | | Water Solubility | Reacts with water. | | Exposure limits | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| 3-ETHOXY-3-OXOPROPYLZINC BROMIDE Usage And Synthesis |
| Uses | 3-Ethoxy-3-oxopropylzinc bromide is a reagent used to insert ethyl propanoate group to the substrate. It can be used in:- Synthesis of γ-keto esters from aryl chlorides.
- Synthesis of sulfones from 1,4-diazabicyclo[2.2.2]octane bis(sulfur dioxide) (DABSO) and alkyl halides.
- Negishi cross-couplings with aryl vinyl phosphates to synthesize 1,1-disubstituted alkenes.
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| 3-ETHOXY-3-OXOPROPYLZINC BROMIDE Preparation Products And Raw materials |
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