Other grades of this product :
| SLAP 5-TMS Basic information |
| Product Name: | SLAP 5-TMS | | Synonyms: | SLAP 5-TMS TM >=95%;SLAP 5-TMS TM;Ethanamine, 2-[[bis(trimethylsilyl)methyl]thio]- | | CAS: | 2084112-39-8 | | MF: | C9H25NSSi2 | | MW: | 235.54 | | EINECS: | | Product Categories: | | Mol File: | 2084112-39-8.mol |
| SLAP 5-TMS Chemical Properties |
| Boiling point | 253.6±40.0 °C(Predicted) | | density | 0.9126 | | storage temp. | 2-8°C | | form | suspension | | pka | 9.30±0.10(Predicted) |
| RIDADR | UN 1993BE 3 / PGII |
| SLAP 5-TMS Usage And Synthesis |
| Uses | When used with aliphatic or aromatic aldehydes, this silicon amine protocol SLAP reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions. |
| SLAP 5-TMS Preparation Products And Raw materials |
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