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| Ethanamine, 2-[(trimethylsilyl)methoxy]- Basic information |
| Ethanamine, 2-[(trimethylsilyl)methoxy]- Chemical Properties |
| Boiling point | 159.6±15.0 °C(Predicted) | | density | 0.849±0.06 g/cm3(Predicted) | | storage temp. | 2-8°C | | pka | 9.05±0.10(Predicted) |
| Ethanamine, 2-[(trimethylsilyl)methoxy]- Usage And Synthesis |
| Uses | When used with aliphatic or aromatic aldehydes, this silicon amine protocol (SLAP) reagent enables the photomediated synthesis of thiomorpholines and thiazepanes. For photocatalytic cross-coupling with this SLAP Reagent, Ir[(ppy)2dtbbpy]PF6 (747769) is used with a recommended starting combination of Lewis acids Bi(OTf)3 (633305) and Cu(OTf)2 (283673) prior to subsequent substrate-specific optimization. This product was introduced in collaboration with the Bode Research Group and provides a tin-free alternative to SnAP (tin amine protocol) reagents and is well-suited for scale-up reactions. |
| Ethanamine, 2-[(trimethylsilyl)methoxy]- Preparation Products And Raw materials |
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