P-XYLOQUINONE

P-XYLOQUINONE
  • CAS No.:137-18-8
Other grades of this product :
P-XYLOQUINONE Basic information
Product Name:P-XYLOQUINONE
Synonyms:2,5-Dimethyl-p-benzoquinone,99%;2,5-DiMethyl-p-benzoquinone, 99% 5GR;2,5-Dimethyl-1,4-benzoquinone >=98.0%;p-Xyloquinone;2,5-Dimethylcyclohexa-2,5-diene-1,4-dione;2,5-Dimethyl-1,4-benzoquinone 2,5-Dimethyl-p-quinone Phlorone;Phlorone-quinone;XYLOQUINONE
CAS:137-18-8
MF:C8H8O2
MW:136.15
EINECS:205-283-6
Product Categories:Building Blocks;C7 to C8;Carbonyl Compounds;Chemical Synthesis;Ketones;Organic Building Blocks;Benzoquinones
Mol File:137-18-8.mol
P-XYLOQUINONE Chemical Properties
Melting point 123-125 °C
Boiling point 69-80℃
density 1.1150 (rough estimate)
refractive index 1.5090 (estimate)
storage temp. 2-8°C
solubility toluene: soluble0.5g/10 mL, clear to faintly turbid, yellow to brown
form Crystalline Powder
color Yellow to brown
BRN 2041348
CAS DataBase Reference137-18-8
EPA Substance Registry System2,5-Cyclohexadiene-1,4-dione, 2,5-dimethyl- (137-18-8)
Safety Information
Hazard Codes Xn
Risk Statements 22-36/37/38
Safety Statements 26-37/39
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
RTECS DK4800000
HS Code 29146990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
P-XYLOQUINONE Usage And Synthesis
Chemical Propertiesyellow to brown crystalline powder
Uses2,5-Dimethyl-1,4-benzoquinone may be used in a key step involved in the total synthesis of (?)-cyathin A3.
Synthesis Reference(s)Synthetic Communications, 25, p. 1669, 1995 DOI: 10.1080/00397919508015851The Journal of Organic Chemistry, 53, p. 5453, 1988 DOI: 10.1021/jo00258a010
General Description2,5-Dimethyl-1,4-benzoquinone is a quinone derivative. Its reaction with jack bean urease in phosphate buffer, pH 7.8 has been studied. It is present as one of the component of defensive secretion of opilionid Acanthopachylus aculeatus. It has been investigated as inhibitor of jack bean urease in 50mM phosphate buffer, pH 7.0.
Purification MethodsCrystallise the quinone from EtOH. [Beilstein 7 IV 2090.]
P-XYLOQUINONE Preparation Products And Raw materials

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