CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE

CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE
  • CAS No.:21170-10-5
Other grades of this product :
CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE Basic information
Product Name:CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE
Synonyms:rel-(3aR,6aR)-3a,6a-diMethyl-octahydropentalene-2,5-dione;(3aβ,6aβ)-3a,6a-Dimethyloctahydropentalene-2,5-dione;1β,5β-Dimethylbicyclo[3.3.0]octane-3,7-dione;3a,4,6,6a-Tetrahydro-3aα,6aα-dimethyl-2,5(1H,3H)-pentalenedione;3aβ,6aβ-Dimethyltetrahydropentalene-2,5(1H,4H)-dione;CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE;3A,6A-DIMETHYLPERHYDROPENTALENE-2,5-DIONE;cis-tetrahydro-3a,6a-dimethylpentalene-2,5(1H,3H)-dione
CAS:21170-10-5
MF:C10H14O2
MW:166.22
EINECS:244-255-8
Product Categories:chiral;C10;Carbonyl Compounds;Ketones
Mol File:21170-10-5.mol
CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE Chemical Properties
Melting point 228-230 °C(lit.)
Boiling point 254.44°C (rough estimate)
density 1.0060 (rough estimate)
refractive index 1.4930 (estimate)
CAS DataBase Reference21170-10-5(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Safety Statements 24/25
WGK Germany 3
Hazard Note Irritant
HS Code 2914290090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE Usage And Synthesis
Chemical Propertieswhite to light yellow crystal powde
Synthesis Reference(s)Tetrahedron Letters, 9, p. 4885, 1968 DOI: 10.1016/S0040-4039(00)72784-5
General DescriptionOlefination of cis-1,5-dimethylbicyclo[3.3.0]octane-3,7-dione with (carbethoxyethylidene)triphenylphospharane under controlled microwave heating has been investigated. It reacts with carbon disulfide, strong base and an alkylating agent in dipolar aprotic solvents to yield racemic mixtures of 2-dialkylthio-methylene compounds.
CIS-1,5-DIMETHYLBICYCLO[3.3.0]OCTANE-3,7-DIONE Preparation Products And Raw materials

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