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| 1-METHOXY-1,3-CYCLOHEXADIENE Basic information |
| Product Name: | 1-METHOXY-1,3-CYCLOHEXADIENE | | Synonyms: | 1-METHOXY-1,3-CYCLOHEXADIENE;2,3-DIHYDROANISOLE;1,3-Cyclohexadien-1-yl methyl ether;1,3-Cyclohexadiene, 1-methoxy-;1-methoxycyclohexa-1,3-diene;1-METHOXY-1,3-CYCLOHEXADIENE, TECH., 65%;1-Methoxy-1,3-cyclohexadiene,2,3-Dihydroanisole;1-Methoxy-1,3-cyclohexadiene technical grade, 65% | | CAS: | 2161-90-2 | | MF: | C7H10O | | MW: | 110.15 | | EINECS: | 218-483-3 | | Product Categories: | | Mol File: | 2161-90-2.mol |
| 1-METHOXY-1,3-CYCLOHEXADIENE Chemical Properties |
| Melting point | 96-97 °C | | Boiling point | 40 °C/15 mmHg (lit.) | | density | 0.929 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.488(lit.) | | Fp | 80 °F |
| Hazard Codes | Xn | | Risk Statements | 10-20/21/22 | | Safety Statements | 16-33-36/37/39 | | RIDADR | UN 1993 3/PG 3 | | WGK Germany | 3 | | HazardClass | 3.2 | | PackingGroup | III |
| 1-METHOXY-1,3-CYCLOHEXADIENE Usage And Synthesis |
| Uses | 1-Methoxy-1,3-cyclohexadiene was used in the following studies:- Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
- Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
- Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.
| | Synthesis Reference(s) | Tetrahedron Letters, 13, p. 4195, 1972 DOI: 10.1016/S0040-4039(01)94273-X | | General Description | 1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative. |
| 1-METHOXY-1,3-CYCLOHEXADIENE Preparation Products And Raw materials |
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