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| (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Basic information | | Reaction |
| Product Name: | (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) | | Synonyms: | (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE);Diaminocyclohexanediylbispyridinecarboxamide;(1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane;(-)-N,N'-(1R,2R)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98%;(-)-N,N''-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98%;(R,R)-DACH-pyridyl Trost ligand;1R,2R- N,N’-1,2-Diaminocyclohexanediylbis
(2-pyridinecarboxamide);2,6-Bis[(4R)-benzyl-2-oxazolin-2-yl]-pyridine | | CAS: | 218290-24-5 | | MF: | C18H20N4O2 | | MW: | 324.38 | | EINECS: | | Product Categories: | DACH&Trost Series;Chiral Nitrogen | | Mol File: | 218290-24-5.mol |
| (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Chemical Properties |
| Melting point | 170°C | | alpha | -95° (c 1, CH3OH) | | Boiling point | 663.4±50.0 °C(Predicted) | | density | 1.25±0.1 g/cm3(Predicted) | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | Powder | | pka | 12.51±0.40(Predicted) | | color | off-white | | optical activity | [α]20/D -97.0°, c = 1 in methanol |
| (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Usage And Synthesis |
| Reaction |
- Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
- Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers.
| | Uses | Trost Ligands for Asymmetric Allylic Alkylation |
| (-)-N,N'-(1R,2R)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Preparation Products And Raw materials |
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