(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE

CAS No.：219143-92-7

Other grades of this product :

(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Basic information

Reaction

Product Name:	(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE
Synonyms:	(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE;(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))chromium(III)chloride;2,2'-{(1S,2S)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis [4,6-bis(2-methyl-2-propanyl)phenol] - trichlorochromium (1:1);(1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕chromium(Ⅲ) Chloride;-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride;-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium(III) chloride;Chromium,chloro[[2,2'-[(1S,2S)-1,2-cyclohexanediylbis[(nitrilo-kN)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)phenolato-kO]](2-)]-, (SP-5-13)-;2,4-ditert-butyl-6-[[[(1S,2S)-2-[(3,5-ditert-butyl-6-oxido-cyclohexa-2,4-dien-1-ylidene)methylamino]cyclohexyl]amino]methylene]cyclohexa-2,4-dien-1-olate
CAS:	219143-92-7
MF:	C36H52ClCrN2O2
MW:	632.26
EINECS:
Product Categories:	CycloadditionChiral Catalysts, Ligands, and Reagents;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;Privileged Ligands and Complexes;SALENs
Mol File:	219143-92-7.mol

(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Chemical Properties

Melting point	250-255 °C(lit.)
form	Powder
color	brown

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22
Safety Statements	26-36
WGK Germany	3

MSDS Information

(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Usage And Synthesis

Reaction	Catalyst for the asymmetric ring-opening of meso-epoxides and for the kinetic resolution of terminal epoxides. Precatalyst for asymmetric Diels-Alder and hetero Diels-Alder reactions. Catalyst for copolymerization of CO2 and epoxides. Catalyst for enantioselective alkylation of tributyltin enolates. Enantioselective addition of Me2Zn to aldehydes. Enantioselective intramolecular addition of tertiary enamides to ketones. Asymmetric iodocyclization. Catalytic intermolecular linear allylic C-H animation. Cocatalyst for enantioselective ring opening of epoxides with fluoride.
Uses	Rosmarinic acid has been used in study to assess its immunomodulatory effect in a murine model of respiratory allergy induced by the Blomia tropicalis (Bt) mite.
General Description	Rosmarinic acid is commonly used in traditional Uighur medicine for treating cancer.

(1S,2S)-(-)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]CHROMIUM(III)CHLORIDE Preparation Products And Raw materials

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