Product

3-BROMO-4-METHOXYTOLUENE

CAS No.：22002-45-5

Other grades of this product :

3-BROMO-4-METHOXYTOLUENE Basic information

Product Name:	3-BROMO-4-METHOXYTOLUENE
Synonyms:	3-BROMO-4-METHOXYTOLUENE;2-BROMO-4-METHYLANISOLE;2-bromo-1-methoxy-4-methyl-benzen;Benzene, 2-bromo-1-methoxy-4-methyl-;3-Bromo-4-methoxytoluene 98%;1-Methoxy-2-bromo-4-methylbenzene;2-Bromo-4-methyl-1-methoxybenzene;Methyl(2-bromo-4-methylphenyl) ether
CAS:	22002-45-5
MF:	C8H9BrO
MW:	201.06
EINECS:	244-705-3
Product Categories:	Anisoles, Alkyloxy Compounds & Phenylacetates;Bromine Compounds;Aromatic Hydrocarbons (substituted) & Derivatives;Anisole
Mol File:	22002-45-5.mol

3-BROMO-4-METHOXYTOLUENE Chemical Properties

Melting point	15.5 °C(lit.)
Boiling point	124-125 °C20 mm Hg(lit.)
density	1.392 g/mL at 25 °C(lit.)
refractive index	n20/D 1.565(lit.)
Fp	>230 °F
storage temp.	Sealed in dry,Room Temperature
Specific Gravity	1.41
CAS DataBase Reference	22002-45-5(CAS DataBase Reference)
EPA Substance Registry System	2-Bromo-4-methylanisole (22002-45-5)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
HazardClass	IRRITANT
HS Code	2909309090

MSDS Information

Provider	Language
SigmaAldrich	English

3-BROMO-4-METHOXYTOLUENE Usage And Synthesis

Chemical Properties	Clear colourless to light yellow liquid
Uses	2-Bromo-4-methylanisole may be used in the synthesis of: 1,6-bis(2-hydroxy-5-methylphenyl)pyridine (H₂mdppy) 1,8-dimethoxy-4-methylanthra-quinone ethyl 2-(2-methoxy-5-methylphenyl)-2-methyl-4-oxocyclopentanecarboxylate It may be used as starting material in the multi-step synthesis of sesquiterpene (±)-herbertenolide.
Synthesis Reference(s)	Synthetic Communications, 23, p. 779, 1993 DOI: 10.1080/00397919308009839
General Description	2-Bromo-4-methylanisole can be prepared via bromination of 4-methylanisole using poly(4-vinylpyridinium bromochromate).

3-BROMO-4-METHOXYTOLUENE Preparation Products And Raw materials

Preparation Products

1-Bromo-2-methoxy-5-methyl-3-nitro-benzene-->3,4-Dimethoxytoluene

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