CIS-1,2-DIMETHYLCYCLOHEXANE

CIS-1,2-DIMETHYLCYCLOHEXANE
  • CAS No.:2207-01-4
Other grades of this product :
CIS-1,2-DIMETHYLCYCLOHEXANE Basic information
Product Name:CIS-1,2-DIMETHYLCYCLOHEXANE
Synonyms:1,2-cis-DimethyIcyclohexane;1,2-Dimethylcyclohexane, cis;1,cis-2-Dimethylcyclohexane;2-dimethyl-cis-cyclohexan;c-1,2-Dimethylcyclohexane;cyclohexane,1,2-dimethyl-,cis-;dimethylcyclohexane(non-specificname);CIS-1,2-DIMETHYLCYCLOHEXANE
CAS:2207-01-4
MF:C8H16
MW:112.21
EINECS:218-621-2
Product Categories:Heterocycles
Mol File:2207-01-4.mol
CIS-1,2-DIMETHYLCYCLOHEXANE Chemical Properties
Melting point -49.99°C
Boiling point 129-130 °C(lit.)
density 0.796 g/mL at 25 °C(lit.)
vapor pressure 28 mm Hg ( 37.7 °C)
refractive index n20/D 1.436(lit.)
Fp 54 °F
solubility Soluble in acetone, alcohol, benzene, ether, ligroin (Weast, 1986); miscible with cyclohexane and cycloheptane.
pka>14 (Schwarzenbach et al., 1993)
form Liquid
color Colorless to Almost colorless
Water Solubility It is soluble in water. 6.0 g(1)/106 g(2) at 25°C.
Henry's Law Constant0.354(atm?m3/mol) at 25 °C (Hine and Mookerjee, 1975)
CAS DataBase Reference2207-01-4(CAS DataBase Reference)
EPA Substance Registry SystemCyclohexane, 1,2-dimethyl-, (1R,2S)-rel- (2207-01-4)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-65
Safety Statements 9-16-33-62
RIDADR UN 2263 3/PG 2
WGK Germany 3
TSCA Yes
HazardClass 3
PackingGroup II
ToxicityEC50 (48-h) for Daphnia pulex 3,235 μg/L (Smith et al., 1988).
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
CIS-1,2-DIMETHYLCYCLOHEXANE Usage And Synthesis
Chemical PropertiesClear, colorless, flammable liquid with a mild characteristic odor.
General Descriptioncis-1,2-Dimethylcyclohexane has been oxidized by O2 in the presence of iron(II)-bispidine complexes. It has been known to form plastic crystals which can be supercooled to show a glass transition at a temperature Tg.
SourceComponent of gasoline (quoted, Verschueren, 1983)
Environmental fateChemical/Physical. Complete combustion in air yields carbon dioxide and water vapor. cis-1,2- Dimethylcyclohexane will not hydrolyze because it has no hydrolyzable functional group.
CIS-1,2-DIMETHYLCYCLOHEXANE Preparation Products And Raw materials
Preparation ProductsCyclohexane, 1,2-dimethyl-, (1R,2R)--->ISOPROPYLCYCLOPENTANE-->3,4-DIMETHYLCYCLOHEXANOL

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