BENZYLOXYACETONE

BENZYLOXYACETONE
  • CAS No.:22539-93-1
Other grades of this product :
BENZYLOXYACETONE Basic information
Product Name:BENZYLOXYACETONE
Synonyms:1-BENZYLOXY-2-PROPANONE;BENZYLOXYACETONE;1-(Benzyloxy)acetone;1-(Benzyloxy)propane-2-one;1-(Benzyloxy)propan-2-one;2-Propanone, 1-(phenylMethoxy)-;Benzyloxyacetone 90%;1-phenylmethoxy-2-propanone
CAS:22539-93-1
MF:C10H12O2
MW:164.2
EINECS:
Product Categories:
Mol File:22539-93-1.mol
BENZYLOXYACETONE Chemical Properties
Boiling point 259 °C (lit.)
density 1.04 g/mL at 25 °C (lit.)
refractive index n20/D 1.512(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
Safety Information
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
BENZYLOXYACETONE Usage And Synthesis
UsesBenzyloxyacetone (1-Benzyloxy-2-propanone) may be used in the synthesis of:
  • 7-benzyloxy-6-methyl-5-hepten-1-yne
  • (Z)-2-methylhept-2-en-6-yn-1-o1
  • (S)-(+)-1,2-propanediol, 1-benzyl ether
It may be used as a starting material in synthesizing (2S,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane and (2R,4RS)-4-acetoxy-2-[(benzyloxy)methyl]-2-methyldioxolane.
General DescriptionBenzyloxyacetone (α-Benzyloxyacetone) is an α-substituted acetone. It undergoes direct aldol reaction with 4-nitrobenzaldehyde in the presence of (S)-BINAM-L-prolinamide/benzoic acid to form predominantly the syn-diasteroisomer.
BENZYLOXYACETONE Preparation Products And Raw materials
Preparation Productsethyl 3-(benzyloxy)-4-oxo-4H-pyran-2-carboxylate

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