(4-Methoxyphenyl)dimethylsilanol

(4-Methoxyphenyl)dimethylsilanol
  • CAS No.:22868-26-4
Other grades of this product :
(4-Methoxyphenyl)dimethylsilanol Basic information
Product Name:(4-Methoxyphenyl)dimethylsilanol
Synonyms:(4-METHOXYPHENYL)DIMETHYLSILANOL;Silanol, 1-(4-methoxyphenyl)-1,1-dimethyl-;(4-Methoxyphenyl)dimethylsilanol 96%
CAS:22868-26-4
MF:C9H14O2Si
MW:182.29
EINECS:
Product Categories:Chemical Synthesis;Organometallic Reagents;Organosilicon;Silanols
Mol File:22868-26-4.mol
(4-Methoxyphenyl)dimethylsilanol Chemical Properties
Boiling point 82 °C(Press: 0.004 Torr)
density 1.101 g/mL at 25 °C
refractive index n 20/D 1.522
Fp 110 °C
storage temp. 2-8°C
pka14.49±0.53(Predicted)
Safety Information
WGK Germany 3
MSDS Information
(4-Methoxyphenyl)dimethylsilanol Usage And Synthesis
Uses(4-Methoxyphenyl)dimethylsilanol is a useful silicon nucleophile for Pd-catalyzed cross-coupling.
Uses(4-Methoxyphenyl)dimethylsilanol can be used:
  • As a starting material in the Pd-catalyzed cross-coupling reactions with various aryl halides to obtain biaryl compounds using Cs2CO3 base.
  • As a starting material to prepare potassium (4-methoxyphenyl)dimethylsilanolate, which in turn is used to synthesize biaryl derivatives by reacting with aryl bromides.
  • As a co-catalyst along with Mo(CO)6 applicable in the 4-decyne metathesis.
(4-Methoxyphenyl)dimethylsilanol Preparation Products And Raw materials

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