(+)-Bis[(R)-1-phenylethyl]amine

CAS No.：23294-41-9

Important Notice

This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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(+)-Bis[(R)-1-phenylethyl]amine Basic information

Product Name:	(+)-Bis[(R)-1-phenylethyl]amine
Synonyms:	(+)-Bis[(R)-1-phenylethyl]amine, ChiPros;[R-(R,R)]-(+)-Bis(α-methylbenzyl)amine;(+)-Bis[(R)-1-phenylethyl]amine;(+)-Bis[(R)-1-phenylethyl]aMine, ChiPros\|r, 99%, ee 98+%;(R)-bis((R)-1-phenylethyl)aMine;(+)-Bis[(R)-1-phenylethyl]amine 99%;(+)-BIS (R)-1-PHENYLETHYL!AMINE HYDRO-;(+)-Bis[(R)-1-phenylethyl]amine, 99% (99+% EE/GLC)
CAS:	23294-41-9
MF:	C16H19N
MW:	225.34
EINECS:
Product Categories:
Mol File:	23294-41-9.mol

(+)-Bis[(R)-1-phenylethyl]amine Chemical Properties

Melting point	~260 °C
Boiling point	86 °C0.05 mm Hg(lit.)
alpha	199 º (NEAT)
density	0.985 g/mL at 25 °C(lit.)
refractive index	n20/D 1.5523(lit.)
Fp	>230 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
pka	8.79±0.29(Predicted)
optical activity	[α]20/D +199.0°, neat
Water Solubility	Insoluble in water.
BRN	3590931
CAS DataBase Reference	23294-41-9

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36/37
WGK Germany	3
F	3

MSDS Information

(+)-Bis[(R)-1-phenylethyl]amine Usage And Synthesis

Uses

(+)-Bis[(R)-1-phenylethyl]amine play a very extensive role of making chirally optically active drugs and compounds. Also as intermediates.

Uses

(+)-Bis[(R)-1-phenylethyl]amine can be used:

In the synthesis of?β-amino acids.
In the preparation of chiral C(19)-C(26) and C(27)-C(32) moieties of scytophycin C.
To induce enantioselectivity in the deprotonation of prochiral ketones.
As a starting material for the synthesis of chiral phenolate ligands through Mannich condensation reaction.
In the synthesis of chiral phosphoramidite ligands.
To prepare chiral cyclic isoimidium salts, which are further used to synthesize chiral lactones through Diels-Alder reaction.

(+)-Bis[(R)-1-phenylethyl]amine Preparation Products And Raw materials

Raw materials

Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->Toluene-->Acetonitrile-->Sodium borohydride-->p-Toluenesulfonic acid-->Acetophenone-->HEAVY DISTILLATE-->(R)-(+)-1-Phenylethylamine

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