Product

METHYL (PHENYLSULFINYL)ACETATE

CAS No.：14090-83-6

Other grades of this product :

METHYL (PHENYLSULFINYL)ACETATE Basic information

Product Name:	METHYL (PHENYLSULFINYL)ACETATE
Synonyms:	METHYL 2-(PHENYLSULFINYL)ACETATE;METHYL (PHENYLSULFINYL)ACETATE;methyl (phenylsulphinyl)acetate;methyl 2-(phenylsulphinyl)acetate;METHYL (+/-)-(PHENYLSULFINYL)ACETATE, 98 %;Acetic acid, (phenylsulfinyl)-, methyl ester;Methyl 2-phenylsulfinylacetate 98%;(Phenylsulfinyl)acetic acid methyl ester
CAS:	14090-83-6
MF:	C9H10O3S
MW:	198.24
EINECS:	237-936-6
Product Categories:	Organic Building Blocks;Sulfoxides;Sulfur Compounds;Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfur Compounds
Mol File:	14090-83-6.mol

METHYL (PHENYLSULFINYL)ACETATE Chemical Properties

Melting point	52-54 °C(lit.)
Boiling point	130-131 °C0.5 mm Hg(lit.)
density	1.3339 (rough estimate)
refractive index	1.5250 (estimate)
Fp	>230 °F
BRN	1953383

Safety Information

Safety Statements	22-24/25
WGK Germany	3

MSDS Information

Provider	Language
SigmaAldrich	English

METHYL (PHENYLSULFINYL)ACETATE Usage And Synthesis

Uses	Undergoes condensation reactions with aldehydes to form vinylic sulfoxides.1
Uses	Anion of methyl 2-phenylsulfinylacetate has been employed in the synthesis of α,β-unsaturated esters.
General Description	Anion of methyl 2-phenylsulfinylacetate undergoes facile alkylative elimination under solid-liquid phase-transfer conditions to afford ring-substituted cinnamates. Methyl 2-phenylsulfinylacetate undergoes condensation reactions with aldehydes to form vinylic sulfoxides.

METHYL (PHENYLSULFINYL)ACETATE Preparation Products And Raw materials

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