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| (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Basic information |
| Product Name: | (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) | | Synonyms: | (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II);(S)-AMAC;Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)-;(S,S)-AMAC | | CAS: | 259259-80-8 | | MF: | C32H38CoN2O4 | | MW: | 573.59 | | EINECS: | | Product Categories: | Asymmetric Synthesis;Catalysts for Organic Synthesis;Classes of Metal Compounds;Co (Cobalt) Compounds;Homogeneous Catalysts;Metal Complexes;Synthetic Organic Chemistry;Transition Metal Compounds | | Mol File: | 259259-80-8.mol |
| (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Chemical Properties |
| Melting point | 242-246°C | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | powder to crystal | | color | Orange to Brown | | optical activity | [α]/D 309°, c = 0.1 in chloroform |
| (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Usage And Synthesis |
| Uses | Catalyst for:- Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
- Enantioselective borohydride reduction
- Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
- Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones
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| (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Preparation Products And Raw materials |
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