| (1S)-(+)-CAMPHORQUINONE Basic information |
| Product Name: | (1S)-(+)-CAMPHORQUINONE |
| Synonyms: | 3-dione,1,7,7-trimethyl-,(1S)-Bicyclo[2.2.1]heptane-2;7,7-trimethyl-3-dion(1s)-bicyclo[2.2.1]heptane-1;S-(+)-CAMPHORQUINONE;CAMPHORQUINONE, -S-(+)-;(+)-CAMPHORQUINONE;L-(+)-CAMPHORQUINONE;L-CAMPHORQUINONE;L-2, 3-BORNANEDIONE |
| CAS: | 2767-84-2 |
| MF: | C10H14O2 |
| MW: | 166.22 |
| EINECS: | 220-446-1 |
| Product Categories: | Bicyclic Monoterpenes;Biochemistry;Terpenes;Ring Systems |
| Mol File: | 2767-84-2.mol |
| (1S)-(+)-CAMPHORQUINONE Chemical Properties |
| Melting point | 197-201 °C(lit.) |
| alpha | +100° (20/D)(c=1.9, C6H5CH3) |
| Boiling point | 234.44°C (rough estimate) |
| density | 0.9817 (rough estimate) |
| refractive index | 1.4859 (estimate) |
| form | powder to crystal |
| color | White to Yellow to Orange |
| optical activity | [α]20/D +100°, c = 1.9 in toluene |
| BRN | 2613999 |
| CAS DataBase Reference | 2767-84-2(CAS DataBase Reference) |
| EPA Substance Registry System | Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl-, (1S,4R)- (2767-84-2) |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ALFA | English |
| (1S)-(+)-CAMPHORQUINONE Usage And Synthesis |
| Chemical Properties | YELLOW POWDER |
| Uses | Chiral starting material. |
| Purification Methods | It can be purified by steam distillation, recrystallisation (yellow prisms) from EtOH, *C6H6 or Et2O/pet ether and it can be sublimed in a vacuum. The (±)-quinone forms needles from EtOH, m 197-198o, 203o. [Buxtorf & Flatt Helv Chim Acta 13 1026 1930, Asahena et al. Chem Ber 67 1432 1934, Beiltein 7 I 325.] |
| (1S)-(+)-CAMPHORQUINONE Preparation Products And Raw materials |
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