1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-

1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-
  • CAS No.:28075-50-5
Other grades of this product :
1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE- Basic information
Product Name:1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-
Synonyms:1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE-;Cyclohex-1-en-1-yl triflate, 1-{[(Trifluoromethyl)sulphonyl]oxy}cyclohex-1-ene;Cyclohex-1-en-1-yl trifluoromethanesulphonate;1-Cyclohexenyl trifluoroMethanesulfonate 97%;cyclohexenyl triflate;cyclohex-1-en-1-yl trifluoromethanesulfonate;Methanesulfonic acid, 1,1,1-trifluoro-, 1-cyclohexen-1-yl ester
CAS:28075-50-5
MF:C7H9F3O3S
MW:230.2
EINECS:
Product Categories:Organic Building Blocks;Organic Triflates;Sulfur Compounds
Mol File:28075-50-5.mol
1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE- Chemical Properties
Boiling point 84-87 °C/4 mmHg (lit.)
density 1.315 g/mL at 25 °C (lit.)
Fp 160 °F
storage temp. 2-8°C
form Liquid
color Colorless to yellow
Safety Information
RIDADR NA 1993 / PGIII
WGK Germany 3
HS Code 2904990090
MSDS Information
1-CYCLOHEXEN-1-YL TRIFLUOROMETHANE- Usage And Synthesis
UsesCyclohex-1-en-1-yl Trifluoromethanesulfonate is used a reactant in the regioselective preparation of phenylpyrrolidines via C-H functionalization of amines with aryl halides.
Synthesis Reference(s)The Journal of Organic Chemistry, 51, p. 277, 1986 DOI: 10.1021/jo00352a039
General Description1-Cyclohexenyl trifluoromethanesulfonate, also known as 1-cyclohexenyl triflate, is a cyclohexenyl sulfonate. Its trifluoromethylation reaction in the presence of different monodentate biaryl phosphine ligands has been investigated. The asymmetric Heck reaction of 1-cyclohexenyl trifluoromethanesulfonate using palladium complexes of phosphine oxazoline ligand has been studied.

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