(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
  • CAS No.:284472-79-3
Other grades of this product :
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Basic information
Reaction
Product Name:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos;97% (S)-PipPhos;1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine;(S)-PipPhos;1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-piperidine;(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine 97%;-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl);1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin- 4-ylpiperidine,99%e.e.
CAS:284472-79-3
MF:C25H22NO2P
MW:399.43
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:284472-79-3.mol
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties
Melting point 206-213 °C
Boiling point 597.5±33.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka1.67±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
Safety Information
MSDS Information
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Usage And Synthesis
Reaction
  1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
  2. Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts. 
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials

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