Ethyl ziram

Ethyl ziram
  • CAS No.:14324-55-1
Other grades of this product :
Ethyl ziram Basic information
Product Name:Ethyl ziram
Synonyms:ZDEC;ZINC DIETHYLDITHIOCARBAMATE;ZINC N,N-DIETHYLDITHIOCARBAMATE;ETHYL ZIMATE;DIETHYLDITHIOCARBAMIC ACID ZINC SALT;Zinc two ethyl two;Accelerator EZ powder;AcceleratorZDC
CAS:14324-55-1
MF:C10H20N2S4Zn
MW:361.93
EINECS:238-270-9
Product Categories:Organometallics;Classes of Metal Compounds;Transition Metal Compounds;Zn (Zinc) Compounds;organic intermediates
Mol File:14324-55-1.mol
Ethyl ziram Chemical Properties
Melting point 178-181 °C (lit.)
Boiling point 330.6°C (estimate)
density 1,48 g/cm3
vapor pressure 0.007Pa at 25℃
Fp 204°(400°F)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form solid
Specific Gravity1.48
color White
Water Solubility Insoluble in water. Soluble in benzene carbon disulfide and organic liquids.
Hydrolytic Sensitivity4: no reaction with water under neutral conditions
InChIKeyRKQOSDAEEGPRER-UHFFFAOYSA-L
LogP3.11
CAS DataBase Reference14324-55-1(CAS DataBase Reference)
NIST Chemistry ReferenceBis(diethyldithiocarbamate)zinc complex(14324-55-1)
EPA Substance Registry SystemEthyl ziram (14324-55-1)
Safety Information
Hazard Codes Xn,N
Risk Statements 22-36/37/38-43-50/53
Safety Statements 24-37-60-61
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS ZH0350000
TSCA Yes
HazardClass 6.1
PackingGroup III
HS Code 29302000
Hazardous Substances Data14324-55-1(Hazardous Substances Data)
ToxicityLD50 orl-rat: 3340 mg/kg 28ZPAK -,11,72
MSDS Information
ProviderLanguage
Zinc bis(diethyldithiocarbamate) English
SigmaAldrich English
ALFA English
Ethyl ziram Usage And Synthesis
Chemical PropertiesWhite powder. Soluble in carbon disulfide, benzene, and chloroform; insoluble in water.
UsesRubber vulcanization accelerator, especially for latex foam; heat stabilizer for polyethylene.
UsesDiethyldithiocarbamate zinc is a rubber component used as a vulcanization accelerator. It can be responsible for rubber dermatitis in healthcare personnel. It was contained in the "carba-mix".
UsesZinc diethyldithiocarbamate is a chelating ligand. It is used as a common accelerator to latex. A fast curing primary or secondary effective ultra-accelerator for natural and synthetic latex compounds.
HazardStrong irritant to eyes and mucous membranes.
Flammability and ExplosibilityNotclassified
Contact allergensDiethyldithiocarbamate zinc is a rubber component used as a vulcanization accelerator. Oxidation of this carbamate leads to tetraethylthiuram disulfide. It can be responsible for rubber dermatitis in health personnel. It was contained in “carba-mix.”
Safety ProfilePoison by intraperitoneal route.Moderately toxic by ingestion and subcutaneous routes.Severe irritant to eyes, nose, and throat. Questionablecarcinogen with experimental carcinogenic andtumorigenic data. Mutation data reported. When heated todecompos
Purification MethodsCrystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. It also crystallises from xylene, m 180o. [Beilstein 4 II 613.] TOXIC.
Ethyl ziram Preparation Products And Raw materials
Raw materialsDiethylamine-->Zinc sulphate-->Sodium formate-->Diethyl disulfide

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