Product

PHENETHYLZINC BROMIDE

CAS No.：308796-14-7

Other grades of this product :

PHENETHYLZINC BROMIDE Basic information

Product Name:	PHENETHYLZINC BROMIDE
Synonyms:	PHENETHYLZINC BROMIDE;phenethylzinc bromide solution;Phenethylzinc bromide solution 0.5 in THF;PHENETHYLZINC BROMIDE, 0.5M SOLUTION IN;2-Phenylethylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;Phenethylzinc bromide solution 0.5 M in THF;2-Phenylethylzinc bromide;Phenethylzinc bromide, 0.50 M in THF
CAS:	308796-14-7
MF:	C8H9BrZn
MW:	250.45
EINECS:
Product Categories:	Chemical Synthesis;Organometallic Reagents;Alkyl;Organozinc Halides;Organozinc Halides;Rieke and Organozinc Reagents;Reike and Organozinc Reagents
Mol File:	308796-14-7.mol

PHENETHYLZINC BROMIDE Chemical Properties

Boiling point	65 °C
density	0.965 g/mL at 25 °C
Fp	1 °F
storage temp.	2-8°C
Water Solubility	Reacts with water.
Sensitive	Air Sensitive
Exposure limits	ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference	308796-14-7

Safety Information

Hazard Codes	F,Xn
Risk Statements	14-19-22-36/38-40-36/37-11
Safety Statements	16-26-33-36-36/37
RIDADR	UN 2056 3/PG 2
WGK Germany	1
HazardClass	4.3

MSDS Information

Provider	Language
SigmaAldrich	English

PHENETHYLZINC BROMIDE Usage And Synthesis

Uses

Phenethylzinc bromide can be used as a reagent:

In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
To synthesize benzyl substituted thienopyrimidine derivatives.

PHENETHYLZINC BROMIDE Preparation Products And Raw materials

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