(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%

CAS No.：145214-59-1

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(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Basic information

Reaction

Product Name:	(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyms:	(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis(di-2-furylphosphine);(S)-2-Furyl-MeOBIPHEP, SL-A108-2, (S)-(-)-2,2μ-Bis(di-2-furylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl;(S)-(-)-2,2''-BIS(DI-2-FURANYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;SL-A108-2;(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(di-2-furylphosphine) >=97%, optical purity ee: >=99%;[2-[2-[bis(furan-2-yl)phosphanyl]-6-methoxyphenyl]phenyl]-bis(furan-2-yl)phosphane
CAS:	145214-59-1
MF:	C30H24O6P2
MW:	542.46
EINECS:
Product Categories:	Chiral Phosphine;MeOBIPHEP Series
Mol File:	145214-59-1.mol

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties

Boiling point	587.5±50.0 °C(Predicted)
form	Powder
color	off-white
Stability:	store cold
CAS DataBase Reference	145214-59-1

Safety Information

WGK Germany	3
HS Code	29321900

MSDS Information

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Usage And Synthesis

Reaction	In many respects the catalytic profile of the MeO-BIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions. Stereocontrol in palladium-catalyzed propargylic substitutions: kinetc resolution to give enantioenriched 1,5-enynes and propargyl acetates. Study of enantioselective catalysis of nitroso-Diels-Alder reaction on solid support.
Chemical Properties	White powder
Uses	Atropisomeric MeOBIPHEP ligands
General Description	sold in collaboration with Solvias AG

(S)-(-)-2,2'-Bis(di-2-furanylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials

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