1,6-DIPHENOXY-2,4-HEXADIYNE

1,6-DIPHENOXY-2,4-HEXADIYNE
  • CAS No.:30980-37-1
Other grades of this product :
1,6-DIPHENOXY-2,4-HEXADIYNE Basic information
Product Name:1,6-DIPHENOXY-2,4-HEXADIYNE
Synonyms:1,6-DIPHENOXY-2,4-HEXADIYNE;LABOTEST-BB LT00454077;TIMTEC-BB SBB008721;6-phenoxyhexa-2,4-diynoxybenzene;1,6-DIPHENOXY-2,4-HEXADIYNE, 98%1,6-DIPHENOXY-2,4-HEXADIYNE, 98%1,6-DIPHENOXY-2,4-HEXADIYNE, 98%1,6-DIPHENOXY-2,4-HEXADIYNE, 98%;Benzene, 1,1'-[2,4-hexadiyne-1,6-diylbis(oxy)]bis-
CAS:30980-37-1
MF:C18H14O2
MW:262.3
EINECS:
Product Categories:
Mol File:30980-37-1.mol
1,6-DIPHENOXY-2,4-HEXADIYNE Chemical Properties
Melting point 80-81°C
Boiling point 443.1±30.0 °C(Predicted)
density 1.135±0.06 g/cm3(Predicted)
BRN 1886340
CAS DataBase Reference30980-37-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-36/37
RIDADR 1325
WGK Germany 3
HS Code 29093090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
1,6-DIPHENOXY-2,4-HEXADIYNE Usage And Synthesis
Uses1,6-Diphenoxy-2,4-hexadiyne may be used to synthesize the trinuclear derivative with an edge bridging ynenyl ligand on reacting with [Ru3(μ-H)(μ3-η2-apyr)(CO)9] (Hapyr=2-aminopyrimidine).
General Description1,6-Diphenoxy-2,4-hexadiyne (dimerized phenyl propargyl ether, DPPE) is a disubstituted diacetylene. It is reported to be synthesized by the oxidative coupling of phenyl propargyl ether. Its structural and spectroscopic properties have been analyzed using vibrational spectroscopy and quantum-chemical calculations. It is reported to form an organic hydrogen getter in combination with 5% Pd-CaCO3. The two crystalline forms of 1,6-diphenoxy-2,4-hexadiyne have been studied.
1,6-DIPHENOXY-2,4-HEXADIYNE Preparation Products And Raw materials
Raw materialsCopper, (3-phenoxy-1-propynyl)--->Bis(5,5-dimethyl-2-thioxo-1,3,2-dioxaphosphorinan-2-yl)disulfide-->PHENYL PROPARGYL ETHER-->BENZYL AZIDE-->Phenol

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