6-CYANOHEXYLZINC BROMIDE

6-CYANOHEXYLZINC BROMIDE
  • CAS No.:312624-28-5
Other grades of this product :
6-CYANOHEXYLZINC BROMIDE Basic information
Product Name:6-CYANOHEXYLZINC BROMIDE
Synonyms:6-CYANOHEXYLZINC BROMIDE, 0.5M SOLUTIONI N TETRAHYDROFURAN;6-CYANOHEXYLZINC BROMIDE;6-Cyanohexylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;6-cyanohexylzinc bromide solution;6-Cyanohexylzinc bromide solution 0.5 in THF;6-Cyanohexylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles;6-Cyanohexylzinc bromide solution 0.5M in THF;6-Cyanohexylzinc bromide 0.5 M in Tetrahydrofuran
CAS:312624-28-5
MF:C7H12BrNZn
MW:255.47
EINECS:
Product Categories:Alkyl;Organozinc Halides;Reike and Organozinc Reagents
Mol File:312624-28-5.mol
6-CYANOHEXYLZINC BROMIDE Chemical Properties
density 0.944 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
Sensitive Air Sensitive
Exposure limitsACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
Safety Information
Hazard Codes F,Xn
Risk Statements 19-22-36/38-40-36/37-14-11
Safety Statements 16-26-33-36-36/37
RIDADR UN 2056 3/PG 2
WGK Germany 1
HazardClass 4.3
MSDS Information
ProviderLanguage
SigmaAldrich English
6-CYANOHEXYLZINC BROMIDE Usage And Synthesis
Uses6-Cyanohexylzinc bromide is an organozinc compound, which can be used as a reactant in palladium-catalyzed Negishi cross-coupling reaction to construct carbon-carbon bonds by coupling with organic halides or triflates.It can also be used as a reactant to synthesize:
  • Cyanohexyl substituted aryl derivatives by palladium catalyzed coupling reaction with aryl bromides.
  • Methyl 5-(6-cyanohexyl)-3-methylfuran-2-carboxylate, a key intermediate which is used in the preparation of cyclic furfuryl ether via Wittig rearrangement.
6-CYANOHEXYLZINC BROMIDE Preparation Products And Raw materials

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