TETRATHIAFULVALENE

TETRATHIAFULVALENE
  • CAS No.:31366-25-3
Other grades of this product :
TETRATHIAFULVALENE Basic information
Product Name:TETRATHIAFULVALENE
Synonyms:1,3-Dithiole, 2-(1,3-dithiol-2-ylidene)-;1,4,5,8-Tetrathiafulvalen;1,4,5,8-Tetrathiafulvalene;2-(1,3-dithiol-2-ylidene)-1,3-dithiol;Δ2,2μ-Bi-1,3-dithiole, TTF;Delta2,2'-bi-1,3-dithiol;[2,2']-Bi[1,3]-dithioylidene;Tetrathiafulvalene, 99+% 1GR
CAS:31366-25-3
MF:C6H4S4
MW:204.34
EINECS:250-593-7
Product Categories:Functional Materials;TTF Derivatives;Building Blocks;Chemical Synthesis;Heterocyclic Building Blocks;Materials Science;Charge Transfer Complexes for Organic Metals;Donors (Charge Transfer Complexes);Organic and Printed Electronics;Organic Field Effect Transistor (OFET) Materials;Others;p-Type Organic Semiconductors;p-Type Small Molecules;S-Containing
Mol File:31366-25-3.mol
TETRATHIAFULVALENE Chemical Properties
Melting point 116-119 °C (lit.)
Boiling point 90℃ (1 Torr)
density 1.448 (estimate)
refractive index 1.6000 (estimate)
storage temp. 2-8°C
form Crystals or Crystalline Powder
color Orange to brownish
Water Solubility It is insoluble in water. Soluble in organic solvents.
Sensitive Air & Light Sensitive
λmax369nm(CHCl3)(lit.)
Merck 14,9242
BRN 1617956
InChIKeyFHCPAXDKURNIOZ-UHFFFAOYSA-N
CAS DataBase Reference31366-25-3(CAS DataBase Reference)
EPA Substance Registry System1,3-Dithiole, 2-(1,3-dithiol-2-ylidene)- (31366-25-3)
Safety Information
Hazard Codes Xi
Risk Statements 43-52/53
Safety Statements 36/37-61-24/25
RIDADR 3335
WGK Germany 3
10-23
TSCA Yes
HS Code 29309090
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
TETRATHIAFULVALENE Usage And Synthesis
Chemical PropertiesORANGE TO BROWNISH CRYSTALS OR CRYSTALLINE POWDER
UsesElectron donor for supramolecular synthesis,1 charge-transfer complex synthesis2 with 7,7,8,8-tetracyanoquinodimethane (cat. no. 157635), and for electron transfer to diazonium salts.3
UsesMolecular sensors; radical catalyst.
UsesTetrathiafulvalene, holds wide application in HPLC, NMR. This heterocyclic compound contributed to the development of molecular electronics. They are used as a organic super conductors.
General DescriptionTetrathiafulvalene (TTF) is an electron-donor which consists of oligomers, dendrimers and polymers which can be used in the formation of redox macromolecules.
Purification MethodsRecrystallise it from cyclohexane/hexane under an argon atmosphere [Kauzlarich et al. J Am Chem Soc 109 4561 1987]. [Beilstein 19/11 V 380.]
TETRATHIAFULVALENE Preparation Products And Raw materials

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