CIS-3-IODOACRYLIC ACID ETHYL ESTER

CIS-3-IODOACRYLIC ACID ETHYL ESTER
  • CAS No.:31930-36-6
Other grades of this product :
CIS-3-IODOACRYLIC ACID ETHYL ESTER Basic information
Product Name:CIS-3-IODOACRYLIC ACID ETHYL ESTER
Synonyms:ethyl (Z)-3-iodoacrylate;ethyl (Z)-3-iodopropenoate;CIS-3-IODOACRYLIC ACID ETHYL ESTER;ETHYL CIS-3-IODOACRYLATE;Ethyl cis-3-Iodoacrylate (stabilized with Copper chip);(Z)-ethyl 3-iodoacrylate;Ethyl cis-3-iodoacrylate 98%;Ethyl cis-3-Iodoacrylate&nbsp
CAS:31930-36-6
MF:C5H7IO2
MW:226.01
EINECS:
Product Categories:Building Blocks;C2 to C5;C2 to C5;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks;Carbonyl Compounds;Esters
Mol File:31930-36-6.mol
CIS-3-IODOACRYLIC ACID ETHYL ESTER Chemical Properties
Boiling point 85 °C/20 mmHg (lit.)
density 1.765 g/mL at 25 °C (lit.)
refractive index n20/D 1.533(lit.)
Fp 210 °F
storage temp. 2-8°C
solubility Chloroform, Ethyl Acetate (Slightly)
form Oil
color Clear Colourless
CAS DataBase Reference31930-36-6
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
HS Code 29161900
MSDS Information
ProviderLanguage
SigmaAldrich English
CIS-3-IODOACRYLIC ACID ETHYL ESTER Usage And Synthesis
UsesEthyl Cis-?3-?iodoacrylate is a reactant used in the synthesis of complex naphtho(benzo)furans as well as in the cobalt-catayzed cross coupling of functionalized organozinc pivalates.
UsesEthyl cis-3-iodoacrylate may be used in the synthesis of the following:
  • vinyl sulfides
  • (Z)-1-iodohept-1-en-3-ol
  • (E)-1-iodohept-1-en-3-ol
  • (Z)-β-iodoacrolein
  • 6-oxo-M1Guo
General DescriptionEthyl cis-3-iodoacrylate (cis-ethyl-β-iodoacrylate, ethyl (Z)-β-iodoacrylate) is Z-vinyl iodide derivative. It is reported to be prepared from ethyl propiolate by treating with sodium iodide. Its Suzuki coupling reaction with cyclic vinyl boronic acids has been studied.
CIS-3-IODOACRYLIC ACID ETHYL ESTER Preparation Products And Raw materials
Raw materialsETHYL 3-(TRIMETHYLSILYL)PROPIOLATE-->(Z)-(3)-IODOACRYLIC ACID-->Ethanol-->Ethyl propiolate
Preparation ProductsEthyl 4-methoxycinnamate

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