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| PHENYL-BETA-D-GLUCOPYRANOSIDE Basic information |
| Product Name: | PHENYL-BETA-D-GLUCOPYRANOSIDE | | Synonyms: | beta-d-glucopyranosid;beta-d-glucopyranoside,phenyl;phenolglucoside;(2R,3S,4S,5R,6S)-2-(Hydroxymethyl)-6-phenoxy-tetrahydro-2H-pyran-3,4,5-triol;b-D-Glucopyranoside, phenyl;-6-phenoxytetrahydro-2H-pyran-3,4,5-triol;Phenyl β-D-Glucoside Hydrate;(2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-phenoxyoxane-3,4,5-triol | | CAS: | 1464-44-4 | | MF: | C12H16O6 | | MW: | 256.25 | | EINECS: | 215-978-6 | | Product Categories: | Biochemistry;Glucose;Glycosides;Sugars;Glucosidase, beta-Specialty Synthesis;Carbohydrate Synthesis;Enzyme Substrates;Monosaccharides;Substrates by Enzyme | | Mol File: | 1464-44-4.mol |
| PHENYL-BETA-D-GLUCOPYRANOSIDE Chemical Properties |
| Melting point | 176-178 °C(lit.) | | Boiling point | 359.49°C (rough estimate) | | density | 1.2993 (rough estimate) | | refractive index | -70.5 ° (C=2, H2O) | | storage temp. | Sealed in dry,Room Temperature | | solubility | Methanol (Slightly), Water (Slightly, Sonicated) | | pka | 12.70±0.70(Predicted) | | form | Powder | | color | White to Off-white | | optical activity | [α]25/D 70°, c = 1 in H2O | | Water Solubility | Soluble in water | | BRN | 87517 | | Stability: | Stable. Incompatible with strong oxidizing agents. | | CAS DataBase Reference | 1464-44-4(CAS DataBase Reference) | | EPA Substance Registry System | .beta.-D-Glucopyranoside, phenyl (1464-44-4) |
| PHENYL-BETA-D-GLUCOPYRANOSIDE Usage And Synthesis |
| Chemical Properties | white powder | | Uses | Phenyl β-D-glucopyranoside can be used:- As a starting material for the synthesis of various derivatives of β-D-glucopyranosides with potential application as anti-HIV agents.
- As a model for glycosides in the gas phase for their spectroscopic investigation.
- As an internal standard in GC and GC-MS quantitative analyses.
| | Safety Profile | Moderately toxic by intraperitoneal route. When heated to decomposition it emits acrid smoke and irritating vapors. | | Purification Methods | Phenyl--D-glucopyranoside recrystallises from H2O with 2H2O and can be dried in vacuo at 100o/P2O5. The dry preparation has [] 25D -70.7o (c 2, H2O). [Robertson & Waters J Chem Soc 2729 1930, IR: Bunton et al. J Chem Soc 4419 1955, Takahashi Yakugaku Zasshi (J Pharm Soc Jpn) 74 7436 1954, Whixtler & House Anal Chem 25 1463 1953, UV: Lewis J Am Chem Soc 57 898 1935.] It is a substrate for D-glucosidase [deBryne Eur J Biochem 102 257 1979]. [Beilstein 17 III/V 2946.] |
| PHENYL-BETA-D-GLUCOPYRANOSIDE Preparation Products And Raw materials |
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