| 3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Basic information |
| Product Name: | 3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER |
| Synonyms: | ETHYL 3-(3-CHLOROPHENYL)-3-OXOPROPANOATE;ETHYL (3-CHLOROBENZOYL)ACETATE;3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER;Ethyl 2-(3-chlorobenzoyl)acetate;2-[(3-chlorophenyl)-oxomethyl]butanoate;3-Chloro--oxobenzenepropanoic acid ethyl ester;Ethyl (3-chlorobenzoyl)acetate >=97%;3-(3-chlorophenyl)-3-keto-propionic acid ethyl ester |
| CAS: | 33167-21-4 |
| MF: | C11H11ClO3 |
| MW: | 226.66 |
| EINECS: | |
| Product Categories: | C10 to C11;Carbonyl Compounds;Esters;Building Blocks;C10 to C11;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks |
| Mol File: | 33167-21-4.mol |
| 3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Chemical Properties |
| Boiling point | 257-258 °C (lit.) |
| density | 1.213 g/mL at 25 °C (lit.) |
| refractive index | n |
| Fp | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| pka | 9.91±0.46(Predicted) |
| CAS DataBase Reference | 33167-21-4(CAS DataBase Reference) |
| Safety Information |
| WGK Germany | 3 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| 3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Usage And Synthesis |
| Uses | Reagent / reactant involved in:• ;Oxidative cross-coupling via dioxygen activation with indoles1• ;Chlorination and hydrosilylation for synthesis of α-hydroxy β-amino acid derivatives2• ;Precursor for substrates for chiral Lewis base-catalyzed stereoselective reduction with trichlorosilane and water3• ;Intramolecular cyclization for synthesis of dihydrofurans4• ;Rate acceleration of Michael reactions5• ;Cerium ammonium nitrate-mediated oxidative coupling6 |
| Uses | Reagent / reactant involved in:
|
| 3-(3-CHLORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER Preparation Products And Raw materials |
| Raw materials | Ethanol-->3-Chlorobenzoyl chloride-->3-Chlorobenzoic acid-->3'-Chloroacetophenone-->Diethyl carbonate-->Ethyl potassium malonate-->Ethyl bromoacetate |
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