(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole

(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole
  • CAS No.:33878-70-5
Other grades of this product :
(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole Basic information
Product Name:(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole
Synonyms:(S)-(-)-2-Tetrazol-5-ylpyrrolidine, Proline Tetrazole Catalyst;(S)-(-)-5-(2-Pyrrolidinyl)-1H-tetrazole;(S)-(–)-5-(2-Pyrrolidinyl)-1H-tetrazole 96%;(S)-(-)-5-(2-Pyrolidinyl)-1H-tetrazole;1H-Tetrazole, 5-(2S)-2-pyrrolidinyl-;(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole;(S)-2-(1H-Tetrazol-5-yl)pyrrolidine;(S)-2-Tetrazol-5-ylpyrrolidine
CAS:33878-70-5
MF:C5H9N5
MW:139.16
EINECS:
Product Categories:Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:33878-70-5.mol
(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole Chemical Properties
Melting point 253-258 °C
Boiling point 335.4±52.0 °C(Predicted)
density 1.301±0.06 g/cm3(Predicted)
refractive index -8 ° (C=1, MeOH)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
pka3.77±0.10(Predicted)
form powder to crystal
color White to Almost white
optical activity[α]20/D -9.0°, c = 1 in methanol
CAS DataBase Reference33878-70-5
Safety Information
Hazard Codes T
Risk Statements 25-36/37/38
Safety Statements 26-36/37-45
RIDADR UN 2811 6.1/PG 3
WGK Germany 3
HS Code 29339900
MSDS Information
(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole Usage And Synthesis
Chemical PropertiesColorless solid
UsesOrganocatalyst used for:
  • Direct asymmetric aldol reactions between acetone and aldehydes yielding β -hydroxy ketone and for synthesizing 1,1,1-trichloro-2-alkanols
  • Mannich reactions for synthesis fo α -amino acids and generation of 1,4-diamines
  • Conjugate additions of malonates to enones
(S)-5-(Pyrrolidin-2-yl)-1H-tetrazole Preparation Products And Raw materials

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