4,4'-DIPYRIDYL N,N'-DIOXIDE HYDRATE, 98%

CAS No.：338950-86-0

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4,4'-DIPYRIDYL N,N'-DIOXIDE HYDRATE, 98% Basic information

Product Name:	4,4'-DIPYRIDYL N,N'-DIOXIDE HYDRATE, 98%
Synonyms:	4,4'-Dipyridyl N,N'-dioxide hydrate 98%;4-(1-oxidopyridin-4-ylidene)pyridin-1-ium 1-oxide,hydrate;4,4'-Bipyridine] 1,1'-dioxide xhydrate
CAS:	338950-86-0
MF:	C10H8N2O2.2H2O
MW:	224.215
EINECS:
Product Categories:	C9 to C46;Heterocyclic Building Blocks;Heterocyclic Compounds;Pyridines;Building Blocks;C10;Chemical Synthesis;Heterocyclic Building Blocks
Mol File:	338950-86-0.mol

4,4'-DIPYRIDYL N,N'-DIOXIDE HYDRATE, 98% Chemical Properties

Melting point	220 °C (dec.)(lit.)
solubility	water: soluble25mg/mL, clear, yellow

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36

MSDS Information

4,4'-DIPYRIDYL N,N'-DIOXIDE HYDRATE, 98% Usage And Synthesis

Uses

4,4′-Dipyridyl N,N′-dioxide may be used:

as bidentate ligand in the preparation of co-ordination polymers of terbium(III)
as ligand in the preparation of 2D CuII complex, with a stacked wavelike structure, and 3D materials, with CoII and NiII
in the preparation of a Mg-based luminescent MIL-53 metal-organic framework (MOF)

General Description

4,4′-Dipyridyl N,N′-dioxide reacts with various transition-metal salts in MeOH to afford a range of coordination polymers with 1-D chain and 2-D sheet architectures incorporating 36-hxl and 44-sql topologies. 4,4′-Dipyridyl N,N′-dioxide is reported to undergo hydrothermal reaction with d(10) metal ions (Cd²⁺ and Zn²⁺) to form three-dimensional grid-like coordination polymers. The electron density of the halogen-bonded complex of 4,4′-dipyridyl-N,N′-dioxide with 1,4-diiodotetrafluorobenzene at 90K has been studied by X-ray diffraction.

4,4'-DIPYRIDYL N,N'-DIOXIDE HYDRATE, 98% Preparation Products And Raw materials

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