DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE

DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
  • CAS No.:3453-00-7
Other grades of this product :
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Basic information
Product Name:DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE
Synonyms:DIETHYL PHENACYLPHOSPHONATE;DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE;DIETHYL(2-OXO-2-PHENYL)PHOSPHONATE;AIDS139382;Diethyl (2-oxo-2-phenylethyl)phosphonate, 98+ %;diethyl (2-oxo-2-phenethyl)phosphonate;2-Phenyl-2-oxoethylphosphonic acid diethyl ester;α-(Diethoxyphosphinyl)acetophenone
CAS:3453-00-7
MF:C12H17O4P
MW:256.23
EINECS:
Product Categories:C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:3453-00-7.mol
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Chemical Properties
Boiling point 192-193 °C/11 mmHg (lit.)
density 1.179 g/mL at 25 °C (lit.)
refractive index n20/D 1.513(lit.)
Fp >230 °F
form clear liquid
color White to Yellow to Green
CAS DataBase Reference3453-00-7
Safety Information
WGK Germany 3
HS Code 2931499090
MSDS Information
ProviderLanguage
SigmaAldrich English
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Usage And Synthesis
UsesReactant involved in:
  • Asymmetric Michael addition of β-oxo phosphonates to nitro olefins
  • Gem-chlorofluorination of keto phosphonates with subsequent functionalization of the products
  • Cyclocondensation reactions to produce arylphosphonates
  • Diazo transfer reactions for synthesis of diazo-phosphonyl compounds
  • Horner-Wadsworth-Emmons reactions
  • Inverse-electron-demand Diels-Alder reactions
Synthesis Reference(s)Synthetic Communications, 26, p. 2561, 1996 DOI: 10.1080/00397919608004568
DIETHYL (2-OXO-2-PHENYLETHYL)PHOSPHONATE Preparation Products And Raw materials

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