Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)

Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
  • CAS No.:346457-41-8
Other grades of this product :
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Basic information
Product Name:Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II)
Synonyms:Dimethylammoniumdichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II);(R)-Ru(OAc)2(BINAP);Dimethylammonium dichlorotri(chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos)}2(Cl)3];(R)-[(RuCl(SEGPHOS))2(μ-Cl)3][NH2Me2];(R)-[(RUCL(SEGPHOS)2(Μ-CL)3[NH2ME2];[NH2Me2][(RuCl((R)-segphos(regR)))2(mu-Cl)3];(R)-[(RuCl(SEGPHOS(R)))2(mu-Cl)3][NH2Me2];[NH2ME2][(RUCL((R)-SEGPHOS))2(Μ-CL)3]
CAS:346457-41-8
MF:2C38H28O4P2.C2H7N.Cl.Cl3Ru2.ClH
MW:1646.66
EINECS:
Product Categories:Ru
Mol File:346457-41-8.mol
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Chemical Properties
Melting point >100°C
storage temp. 2-8°C
Water Solubility Insoluble in water
form Powder
color light brown
Sensitive air sensitive
CAS DataBase Reference346457-41-8
Safety Information
WGK Germany 3
MSDS Information
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Usage And Synthesis
UsesTakasago Ligands and Complexes for Asymmetric Reactions
General Description(R)-[(RuCl(SEGPHOS?))2(μ-Cl)3][NH2Me2] is a ruthenium-based catalyst generally used in the asymmetric hydrogenation reactions of ketones. SEGPHOS?, the chiral ligand and its ruthenium-based catalysts are developed and commercialized by Takasago International Corporation.
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Preparation Products And Raw materials

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