Irisone

Irisone
  • CAS No.:14901-07-6
Other grades of this product :
Irisone Basic information
Product Name:Irisone
Synonyms:3-Buten-2-one, 4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (E)-;4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-on;4-(2,6,6-trimethyl-1-cyclohexen-1-yl)-3-buten-2-one (beta-ionone);4-(2,6,6-trimethyl-1-cyclohexene-1-yl)-3-buten-2-one;4-(2,6,6-Trimethyl-1-cyclohexen-l-yl)-3-buten-2-one;4-(2,6,6-trimethyl-cyclohex-1-enyl)-but-3-en-2-one;-Ionone,boronione;5,7-Megastigmadien-9-one
CAS:14901-07-6
MF:C13H20O
MW:192.3
EINECS:238-969-9
Product Categories:Pharmaceutical Intermediates;Biochemistry;Monocyclic Monoterpenes;Terpenes
Mol File:14901-07-6.mol
Irisone Chemical Properties
Melting point -49°C
Boiling point 126-128 °C12 mm Hg(lit.)
density 0.945 g/mL at 25 °C(lit.)
vapor pressure 1.706Pa at 25℃
refractive index n20/D 1.52(lit.)
FEMA 2595 | BETA-IONONE
Fp 230 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
pka0[at 20 ℃]
form Liquid
color Clear slightly yellow to yellow
Water Solubility SLIGHTLY SOLUBLE
Merck 14,5056
JECFA Number389
BRN 1909544
Stability:Light Sensitive
LogP1.903 at 27℃
CAS DataBase Reference14901-07-6(CAS DataBase Reference)
NIST Chemistry Reference4-(2,6,6-Trimethylcyclohex-1-en-1-yl)but-3-en-2-one(14901-07-6)
EPA Substance Registry System4-(2,6,6-Trimethyl-1-cyclohexenyl)-3-buten-2-one (14901-07-6)
Safety Information
Hazard Codes Xi,N
Risk Statements 38-51/53-36/37/38
Safety Statements 61-36/37/39-27-26-24/25
RIDADR UN 3082 9/PG 3
WGK Germany 2
RTECS EN0500000
HS Code 29147000
Hazardous Substances Data14901-07-6(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Irisone English
ACROS English
SigmaAldrich English
ALFA English
Irisone Usage And Synthesis
Descriptionβ-Ionone has a characteristic violet-like odor, more fruity and woody than α-ionone. May be prepared by condensing citral with acetone to form pseudoionone, which is then cyclized by acid-type reagents.
Chemical Propertiesβ-Ionone has a characteristic violet-like odor, more fruity and woody than α-ionone
Chemical Propertiesclear slightly yellow to yellow liquid
OccurrenceReported found in the distillate from flowers of Boronia megatisma Nees. Also reported found in apricot, orange juice, lemon peel oil, guava, grapes, melon, papaya, peach, raspberry, blackberry, carrot, peas, bell pepper, tomato, ginger, peppermint and spearmint oil, milk powder, beef, hop oil, cognac, whiskies, grape wines, tea, passion fruit, plum, beans, mushroom, starfruit, almonds, mango, fenugreek, tamarind, apple and pear brandy, rice bran, quince, prickly pear, sweet potato, buckwheat, corn oil, corn tortillas, loquat, mountain papaya, clary sage and other sources
Usesbeta-Lonone is an essential oil extract from the leaves and flowers of Succisa Pratensis that shows antioxidant and antimicrobial activities against bacteria.
Usesβ-Ionone may be used as a reference standard in the determination of β-ionone in wine using solid-phase extraction followed by gas chromatography with mass spectrometry (GC-MS).
PreparationBy condensing citral with acetone to form pseudoionone, which is then cyclized by acid-type reagents.
Aroma threshold valuesDetection: 0.007 to 205 ppb
Taste threshold valuesTaste characteristics art 10 ppm: woody, sweet, fruity, berry-like with a green berry background
General DescriptionColorless to light yellow liquid with an odor of cedar wood. In very dilute alcoholic solution the odor resembles odor of violets. Used in perfumery.
Air & Water ReactionsSlightly water soluble .
Reactivity ProfileIrisone may react vigorously with oxidizing agents. May react exothermically with reducing agents to release hydrogen gas.
Health HazardACUTE/CHRONIC HAZARDS: Toxic. May cause allergic reaction.
Flammability and ExplosibilityNonflammable
Biochem/physiol ActionsTaste at 1-20 ppm
Irisone Preparation Products And Raw materials

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