Product

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&

CAS No.：357209-32-6

Other grades of this product :

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Basic information

Product Name:	2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&
Synonyms:	2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO&;2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D) OXAZOLIN-2-YL)PYRIDINE;(3aR,8aS)-in-pybox, (3aR,3μaR,8aS,8μaS)-2,2μ-(2,6-Pyridinediyl)bis[3a,8a-dihydro-8H-indeno[1,2-d]oxazole;2,6-Bis((3aR,8aS)-8,8a-dihydro-3aH-indeno[1,2-d]oxazol-2-yl)pyridine;8H-Indeno[1,2-d]oxazole,2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-, (3aR,3'aR,8aS,8'aS)-;(3aR,3'aR,8aS,8'aS)-2,2'-(2,6-pyridinediyl)bis[3a,8a-dihydro-8H-Indeno[1,2-d]oxazole;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine >=94%;2,6-Bis[(3aR,8aS)-(+)-8H-indeno[1,2-d]oxazolin-2-yl)pyridine, >=98%
CAS:	357209-32-6
MF:	C25H19N3O2
MW:	393.44
EINECS:
Product Categories:	BOX series;Chiral Nitrogen
Mol File:	357209-32-6.mol

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Chemical Properties

Melting point	284 °C (dec.)
Boiling point	633.0±55.0 °C(Predicted)
density	1.50±0.1 g/cm3(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	4.35±0.20(Predicted)
optical activity	[α]20/D +386°, c = 1 in methylene chloride(lit.)

Safety Information

Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
HS Code	29349990

MSDS Information

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Usage And Synthesis

Chemical Properties

White powder

Uses

Catalytic ligand used for:

[3+2] cycloaddition of N-tosyl aziridines with electron-rich alkenes via selective carbon-carbon bond cleavage
Enantioselective Mukaiyama-aldol reactions
Enantioselective carbonyl-ene reactions
Cu(I)-catalyzed asymmetric alkynylation of imino esters with terminal alkynes
Asymmetric three-component coupling reactions catalyzed by a Cu/pybox complex
Enantioselective Diels-Alder reaction
Ni-catalyzed cross-coupling reactions

2,6-BIS((3AR,8AS)-8H-INDENO(1,2-D)OXAZO& Preparation Products And Raw materials

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