SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
  • CAS No.:35789-01-6
Other grades of this product :
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Basic information
Product Name:SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Synonyms:SAMARIUM TRIS(HEXAMETHYLDISILAZIDE);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III);Tris[N,N-bis(trimethylsilyl)amide]samarium;Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM;1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt;Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium;samarium tris(hexamethylsilazide);Tris[N,N-bis(trimethylsilyl)amide]samarium [[(CH3)3Si]2N]3Sm FW 631.51 M.p. 93-1060C
CAS:35789-01-6
MF:C18H54N3Si6Sm
MW:631.51
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Precursors by Metal;SamariumVapor Deposition Precursors;Samariun
Mol File:35789-01-6.mol
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Chemical Properties
Melting point 93-106 °C(lit.)
Boiling point 83-4°C/1x10-4mmHg
Fp 36 °F
form solid
Safety Information
Hazard Codes F,C
Risk Statements 11-14/15-34
Safety Statements 16-26-36/37/39-43-45-7/8
RIDADR UN 3396 4.3/PG 2
WGK Germany 3
TSCA No
MSDS Information
ProviderLanguage
SigmaAldrich English
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Usage And Synthesis
UsesReactant for synthesis of:
  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes
Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization
SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Preparation Products And Raw materials

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