METHYL 3-BUTENOATE

METHYL 3-BUTENOATE
  • CAS No.:3724-55-8
Other grades of this product :
METHYL 3-BUTENOATE Basic information
Product Name:METHYL 3-BUTENOATE
Synonyms:3-butenoicacid,methylester;CH2=CHCH2C(O)OCH3;METHYL VINYLACETATE;METHYL 3-BUTENOATE;but-3-enoic acid methyl ester;methyl but-3-enoate;Methyl 3-butenoate 95%
CAS:3724-55-8
MF:C5H8O2
MW:100.12
EINECS:223-076-9
Product Categories:
Mol File:3724-55-8.mol
METHYL 3-BUTENOATE Chemical Properties
Melting point -78.42°C (estimate)
Boiling point 112 °C (lit.)
density 0.939 g/mL at 25 °C (lit.)
refractive index n20/D 1.409(lit.)
Fp 60 °F
BRN 1741732
InChIKeyGITITJADGZYSRL-UHFFFAOYSA-N
NIST Chemistry ReferenceMethyl 3-butenoate(3724-55-8)
EPA Substance Registry System3-Butenoic acid, methyl ester (3724-55-8)
Safety Information
Hazard Codes F
Risk Statements 11
Safety Statements 16
RIDADR UN 3272 3/PG 2
WGK Germany 3
HazardClass 3.1
PackingGroup II
MSDS Information
ProviderLanguage
SigmaAldrich English
METHYL 3-BUTENOATE Usage And Synthesis
UsesMethyl 3-butenoate may be employed for the synthesis of dipeptide olefin isosteres using intermolecular olefin cross-metathesis.
Synthesis Reference(s)Journal of the American Chemical Society, 99, p. 5184, 1977 DOI: 10.1021/ja00457a052Tetrahedron Letters, 14, p. 2433, 1973 DOI: 10.1016/S0040-4039(01)96239-2
General DescriptionMethyl 3-butenoate is an olefin ester. It is reported to undergo Iron carbonyl-promoted isomerization to afford α, β-unsaturated esters. It is one of the reaction products formed during flash vacuum thermolysis of (?)-cocaine. The H2 and CH4 chemical ionization mass spectra of methyl 3-butenoate has been reported.
METHYL 3-BUTENOATE Preparation Products And Raw materials
Raw materials1-Propene, 3-(dimethoxymethoxy)--->Allyl methyl carbonate
Preparation ProductsADIPIC SEMIALDEHYDE METHYL ESTER

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