N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][

CAS No.：376355-58-7

Other grades of this product :

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Basic information

Reaction

Product Name:	N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
Synonyms:	N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][;BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite;N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-
CAS:	376355-58-7
MF:	C28H26NO2P
MW:	439.49
EINECS:
Product Categories:	phosphine-amine ligand;Chiral Phosphine;CPN
Mol File:	376355-58-7.mol

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties

Melting point	99-102 °C
Boiling point	578.4±53.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
pka	-0.31±0.20(Predicted)
form	Powder
color	white
optical activity	[α]/D -250±10°, c = 1 in toluene
Sensitive	moisture sensitive

Safety Information

WGK Germany

MSDS Information

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Usage And Synthesis

Reaction

Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic substituted allylic halides to form branched chiral products from diverse Grignard reagents.
Ligand for the copper catalyzed, highly enantioselective conjugate addition of diethylzinc to eneones and nitro olefins.
Ligand for the nickel catalyzed, highly enantioselective hydrovinylation of alkenes.
Ligand for the rhodium catalyzed, highly enantioselective hydroformylation of vinylarenes.
Ligand for gold catalyzed asymmetric Intramolecular hydroamination of allenes

Uses

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:

In the iridium catalyzed allylic arylation.
To prepare a copper complex (Cu₂X₂L₃), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt₂.

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Preparation Products And Raw materials

Welcome！

Please leave a message for us or use the following ways to contact us, we will reply to you as soon as possible, and provide you with the most sincere service, thank you.

NO. 18 ,Wujiang Road, Wulidian Street, Jiangbei District, Chongqing
+86-23-6139-8061 +86-13650506873
danny@chemdad.com sales@chemdad.com
www.chemdad.com
WhatsApp +86-13650506873