(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

CAS No.：380230-02-4

Other grades of this product :

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Basic information

Reaction

Product Name:	(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
Synonyms:	(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE;(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE;(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%;S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
CAS:	380230-02-4
MF:	C36H30NO2P
MW:	539.6
EINECS:
Product Categories:	Chiral Phosphine;CPN
Mol File:	380230-02-4.mol

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties

Melting point	88-89 °C
alpha	+13.1° (c 1.01, CHCl3)
Boiling point	710.7±63.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
pka	-0.57±0.20(Predicted)
color	off-white
Sensitive	moisture sensitive
InChIKey	LKZPDRCMCSBQFN-UIOOFZCWSA-N

Safety Information

Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3

MSDS Information

Provider	Language
SigmaAldrich	English

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Usage And Synthesis

Reaction

A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
Iridium-catalyzed regioselective and enantioselective allylation of enamines.
Iridium-catalyzed asymmetric allylation of KSAc.

Uses

The product may be used as a ligand in:

Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Preparation Products And Raw materials

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