1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER
  • CAS No.:1515-75-9
Other grades of this product :
1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Basic information
Product Name:1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER
Synonyms:Methyl 2,4-pentadienoate, stabilized with 0.5% hydroquinone, stabilized with 0.5% hydroquinone, 97%;Methyl 2,4-pentadienoate Mixture of cis and trans, >=97.0% (GC);1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER;Methyl 2,4-pentadienoate,1,3-Butadiene-1-carboxylic acid methyl ester, 2,4-Pentadienoic acid methyl ester, Methyl 1,3-butadiene-1-carboxylate;(E)-Methyl 2,4-Pentadienoate;METHYL PENTANEDIENOATE;METHYL 2,4-PENTADIENOATE;METHYL 1,3-BUTADIENE-1-CARBOXYLATE
CAS:1515-75-9
MF:C6H8O2
MW:112.13
EINECS:216-158-0
Product Categories:
Mol File:1515-75-9.mol
1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Chemical Properties
Boiling point 50-52 °C20 mm Hg(lit.)
density 0.964 g/mL at 20 °C
refractive index n20/D 1.484
Fp 37 °C
storage temp. -20°C
BRN 1743332
Safety Information
Hazard Codes Xi
Risk Statements 10-36/37/38-52/53
Safety Statements 26-36-61
RIDADR UN 3272 3/PG 3
WGK Germany 3
8
HazardClass 3.2
PackingGroup III
HS Code 29161995
MSDS Information
ProviderLanguage
SigmaAldrich English
1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Usage And Synthesis
Synthesis Reference(s)Journal of the American Chemical Society, 94, p. 4395, 1972 DOI: 10.1021/ja00767a088Synthesis, p. 534, 1988 DOI: 10.1055/s-1988-27626
General DescriptionMethyl 2,4-pentadienoate undergoes Aza-Morita-Baylis-Hillman reaction with aldimines in DMF in the presence of 3-hydroxyquinuclidine.
1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

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