(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE&

(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE&
  • CAS No.:391860-55-2
Other grades of this product :
(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& Basic information
Product Name:(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE&
Synonyms:(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE&;(11bR, 11μbR)-4,4μ-(Oxydi-2,1-phenylene)bis-dinaphtho[2,1-d:, 1μ, 2μ-f][1,3,2]dioxaphosphepin;R, R-Reetz D-Diphosphonite
CAS:391860-55-2
MF:C52H32O5P2
MW:798.768
EINECS:
Product Categories:
Mol File:391860-55-2.mol
(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& Chemical Properties
Melting point 171-187 °C
optical activity[α]22/D +123°, c = 1 in chloroform
Safety Information
Hazard Codes Xn
Risk Statements 48/20-63-65
Safety Statements 36/37-45-62
RIDADR UN 3175 4.1/PG 2
WGK Germany 3
MSDS Information
(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& Usage And Synthesis
UsesThis diphosphonite ligand has been successfully employed in asymmetric Rh-catalyzed conjugate addition reactions of arylboronic acids to enones, as well as in asymmetric hydrogenation reactions of β-keto esters.
(11BR, 11'BR)-4,4'-(OXYDI-2,1-PHENYLENE& Preparation Products And Raw materials

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