(R)-METHYL BOPHOZ(TM)

(R)-METHYL BOPHOZ(TM)
  • CAS No.:406681-09-2
Other grades of this product :
(R)-METHYL BOPHOZ(TM) Basic information
Reaction
Product Name:(R)-METHYL BOPHOZ(TM)
Synonyms:(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine Methyl BoPhoz;(S)-N-Diphenylphosphino-N-methyl-(R)-2-(diphenylphosphino)ferrocenylüethylamine, (S)-Methyl BoPhoz;(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine;Methyl-BoPhoz, (1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene;(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, (S)-Methyl BoPhoz^t;(S)-Me-Bophoz;(S)-1-[(R)-2-Diphenylphosphinoferrocenyl](N-Methyl)(N-diphenylphosphino)ethylaMine (S)-Me-Bophoz;(1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene
CAS:406681-09-2
MF:C37H29FeNP2
MW:605.44
EINECS:
Product Categories:
Mol File:406681-09-2.mol
(R)-METHYL BOPHOZ(TM) Chemical Properties
Melting point 80-82°C
form solid
color yellow
Safety Information
WGK Germany 3
MSDS Information
ProviderLanguage
ALFA English
(R)-METHYL BOPHOZ(TM) Usage And Synthesis
Reaction
  1. Ligand used in the rhodium-catalyzed, asymmetric hydrogenation of β-amido-vinylphosphonates.
  2. Ligand used in the rhodium or iridium-catalyzed asymmetric hydrogenation of α,β-unsaturated esters.
Chemical PropertiesYellow to orange amorphous solid
UsesMethyl-BoPhoz can be used:
  • As an efficient ligand for asymmetric hydrogenation reactions.
  • To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.
  • To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.
(R)-METHYL BOPHOZ(TM) Preparation Products And Raw materials

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