2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE

2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE
  • CAS No.:472-66-2
Other grades of this product :
2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Basic information
Product Name:2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE
Synonyms:(2,6,6-Trimethyl-1-cyclohexen-1-yl)acetaldehyde;2,6,6-trimethyl-1-cyclohexene-1-acetaldehyd;B-HOMOCYCLOCITRAL;FEMA 3474;2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-ACETALDEHYDE;2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE;2-(2,6,6-triMethylcyclohex-1-en-1-yl)acetaldehyde;2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde technical grade, 80%
CAS:472-66-2
MF:C11H18O
MW:166.26
EINECS:207-454-0
Product Categories:Aldehydes;Building Blocks;C10-C12;Carbonyl Compounds;Chemical Synthesis;Organic Building Blocks
Mol File:472-66-2.mol
2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Chemical Properties
Boiling point 58-59 °C/0.4 mmHg (lit.)
density 0.941 g/mL at 25 °C (lit.)
refractive index n20/D 1.485(lit.)
FEMA 3474 | 2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-ACETALDEHYDE
Fp 191 °F
storage temp. 2-8°C
JECFA Number978
EPA Substance Registry System1-Cyclohexene-1-acetaldehyde, 2,6,6-trimethyl- (472-66-2)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Usage And Synthesis
Uses2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde can be used as a starting material to prepare:
  • (±)-Aeginetolide by oxidation in the presence of meta-chloroperoxybenzoic acid (m-CPBA).
  • (±)-Dihydroactinidiolide (a C11-terpenic lactone) via dehydration of key intermediate aeginetolide.
It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.
Taste threshold valuesTaste characteristics at 15 ppm: cooling, woody, oily, soapy, citrus with a berry, orris-like nuance.
2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE Preparation Products And Raw materials

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