Product

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE

CAS No.：158923-09-2

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(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Basic information

Product Name:	(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE
Synonyms:	(R,R)-1-(DICYCLOHEXYLPHOSPHINO)-2-[1-(DIPHENYLPHOSPHINO)ETHYL]FERROCENE;(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDIPHENYLPHOSPHINE;(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE;(R)1[(1S)2(di-C-hexylphosphino)ferrocen. ]et-diphenylphosphin;(R)1 (1S)2(DI-C-HEXYLPHOSPHINO)FERROCEN&;(R)-(-)-1-[(S)-2-(Dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine,min.97%;(r,r)-1-(dicyclohexylphosphino)-2-[1-(diphenylphosphino)ethyl]ferrocene (acc to cas);(R)-(-)-1-[(S)-2-(DICYCLOHEXYLPHOSPHINO) FERROCENYL]ETHYLDIPHENYLPHOSPHINE, MIN. 97%
CAS:	158923-09-2
MF:	C36H44FeP210*
MW:	594.53
EINECS:
Product Categories:	Chiral Phosphine;Ferrocene Series;organophosphine ligand;Josiphos Series
Mol File:	158923-09-2.mol

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Chemical Properties

alpha	-100° ±5° (c 0.5, CHCl3)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	Powder
color	orange

Safety Information

Risk Statements	36/37/38
Safety Statements	26-36/37/39
WGK Germany	3
F	10
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Usage And Synthesis

Chemical Properties	Red crystal
Uses	(R)-1-[(S_P)-2-(Dicyclohexylphosphino)ferrocenylethyl]diphenylphosphine can be used as a ligand: To prepare iridium metal complex (Ir^IJOSIPHOS), which is used as a catalyst in the asymmetric hydrogenation of 2-phenylquinoxaline. In the preparation of natural products by asymmetric conjugate addition of Grignard reagents to α-substituted cyclic alkenones.
Reactions	1. Ligand for asymmetric hydroformylation reactions 2. Ligand for asymmetric intramolecular amide arylation 3. Ligand for enantioselective 1,6-conjugate addition of Grignard reagents to linear dienolates 4. Ligand for enantioselective synthesis of vicinal dialkyl arrays 5. Ligand for asymmetric conjugate addition of Grignard reagents to chromones .
General Description	sold in collaboration with Solvias AG

(R)-1-[(1S)-2-(DICYCLOHEXYLPHOSPHINO)FERROCENYL]ETHYLDI-PHENYLPHOSPHINE Preparation Products And Raw materials

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