(R)-(-)-HEXAHYDROMANDELIC ACID

(R)-(-)-HEXAHYDROMANDELIC ACID
  • CAS No.:53585-93-6
Other grades of this product :
(R)-(-)-HEXAHYDROMANDELIC ACID Basic information
Product Name:(R)-(-)-HEXAHYDROMANDELIC ACID
Synonyms:(R)-(-)-HEXAHYDROMANDELIC ACID;R(-)-CYCLOHEXYLHYDROXYACETIC ACID;2-CYCLOHEXYLGLYCOLIC ACID;ALPHA-HYDROXYCYCLOHEXANE-ACETIC ACID;CYCLOHEXYL-HYDROXY-ACETIC ACID;D-HEXAHYDROMANDELIC ACID;Cyclohexylglycolic acid;hexahydromandelic acid
CAS:53585-93-6
MF:C8H14O3
MW:158.2
EINECS:
Product Categories:
Mol File:53585-93-6.mol
(R)-(-)-HEXAHYDROMANDELIC ACID Chemical Properties
Melting point 127-129 °C (lit.)
Boiling point 319.3±15.0 °C(Predicted)
density 1.178±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
pka3.86±0.11(Predicted)
optical activity[α]18/D 23°, c = 1 in acetic acid
BRN 3196809
Safety Information
Safety Statements 22-24/25
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
(R)-(-)-HEXAHYDROMANDELIC ACID Usage And Synthesis
Uses(R)-(?)-Hexahydromandelic acid can be used:
  • As an intermediate in the synthesis of antimycobacterial compound pyridomycin analogs.
  • As a model α-hydroxy acid compound in the chirality sensing studies of organic probes using circular dichroism technique.
  • As a starting material in the synthesis of chiral ionic liquids, which are applicable as chiral solvents in asymmetric synthesis and as chiral stationary phases in chromatographic separations.
Purification MethodsIt forms hexagonal clusters on recrystallisation from CCl4 or Et2O. [Wood & Comley J Chem Soc 2638 1924, Lettré et al. Chem Ber 69 1594 1936]. The racemate has m 137.2-137.6o (134-135o) [Smith et al. J Am Chem Soc 71 3772 1949]. [Beilstein R-10 II 5; S-10 II 6.]
(R)-(-)-HEXAHYDROMANDELIC ACID Preparation Products And Raw materials

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