TROPONE

TROPONE
  • CAS No.:539-80-0
Other grades of this product :
TROPONE Basic information
Product Name:TROPONE
Synonyms:TROPONE;cyclohepta-2,4,6-trien-1-one;2,4,6-Cyclo-heptatriene-1-one;2,4,6-Cycloheptatriene-1-one;cyclohepta-2,4,6-trienone;Cycloheptatrienone;Tropon;2,4,6-CYCLOHEPTATRIEN-1-ONE
CAS:539-80-0
MF:C7H6O
MW:106.12
EINECS:208-725-6
Product Categories:
Mol File:539-80-0.mol
TROPONE Chemical Properties
Melting point -7°C
Boiling point 113 °C/15 mmHg (lit.)
density 1.094 g/mL at 25 °C (lit.)
refractive index n20/D 1.615(lit.)
Fp >110°C
storage temp. -20°C
color very deep brown
BRN 1902335
Safety Information
Safety Statements 24/25
WGK Germany 3
10-23
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
TROPONE Usage And Synthesis
UsesTropone has been used in synthesis of:
  • bicyclic δ-lactones via heterocyclic carbine-catalyzed [8+3] annulation pathway
  • 6,7-benzobicyclo [3.2.2] nona-3,6,8-trien-2-one via thermal addition to bezyne
Synthesis Reference(s)Journal of the American Chemical Society, 78, p. 5442, 1956 DOI: 10.1021/ja01601a077The Journal of Organic Chemistry, 29, p. 960, 1964Organic Syntheses, Coll. Vol. 9, p. 396, 1998
General DescriptionMetal-catalyzed [6+3] cycloaddition of tropone with azomethine ylides has been reported.
TROPONE Preparation Products And Raw materials
Preparation ProductsDIMETHYL 3,4-FURANDICARBOXYLATE-->IRON DODECACARBONYL

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