2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE

2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE
  • CAS No.:54781-19-0
Other grades of this product :
2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE Basic information
Product Name:2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE
Synonyms:2-(TRIMETHYLSILYLOXY)-1,3-CYCLOHEXADIENE;2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE;1,5-Cyclohexadienyl(trimethylsilyl) ether;2-(Trimethylsilyloxy)cyclohexa-1,3-diene;1-(Trimethylsilyloxy)-3,4-dihydrobenzene;(cyclohexa-1,5-dien-1-yloxy)triMethylsilane;2-(Trimethylsiloxy)-1,3-cyclohexadiene 95%;1,3-Cyclohexadiene, 2-[(trimethylsilyl)oxy]-
CAS:54781-19-0
MF:C9H16OSi
MW:168.31
EINECS:
Product Categories:Enol Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:54781-19-0.mol
2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE Chemical Properties
Melting point 242-246 °C
Boiling point 65 °C7 mm Hg(lit.)
density 0.899 g/mL at 25 °C(lit.)
refractive index n20/D 1.462(lit.)
Fp 117 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Almost colorless
BRN 2079140
CAS DataBase Reference54781-19-0
Safety Information
Risk Statements 10
Safety Statements 16
RIDADR UN 1993 3/PG 3
WGK Germany 3
10-21
HazardClass 3
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE Usage And Synthesis
Uses2-(Trimethylsiloxy)-1,3-cyclohexadiene may be used as a diene in the synthesis of isoquinuclidinone 2-aza[2.2.2]octa-3,5-dione by reacting with p-toluenesulfonyl cyanide.
General Description2-(Trimethylsiloxy)-1,3-cyclohexadiene ((cyclohexa-1,5-dien-1-yloxy)trimethylsilane) is silyl enol ether of cyclohexenone. The Diels–Alder reactions with dienophiles α-acetoxyacrylonitrile, acrylonitrile and α-chloroacrylonitrile has been studied.
2-(TRIMETHYLSILOXY)-1,3-CYCLOHEXADIENE Preparation Products And Raw materials
Preparation ProductsTrimethyl(phenoxy)silane

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