BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97

BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97
  • CAS No.:57357-20-7
Other grades of this product :
BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97 Basic information
Product Name:BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97
Synonyms:BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97;(di-tert-butylcarbonyloxyiodo)benzol;(Di-tert-butylcarbonyloxyiodo)benzol, 2,2-Dimethylpropanoic acid, phenyliodine complex, Bis(2,2-dimethylpropanoato-O)phenyliodide, Di-(Pivaloyloxy)iodobenzene;Bis(tert-butylcarbonyloxy)iodobenzene 97%;Iodine, bis(2,2-dimethylpropanoato-κO)phenyl-;phenyl-l3-iodanediyl bis(2,2-dimethylpropanoate);2-(2,2-dimethylpropanoyloxy)-3-iodophenyl]2,2-dimethylpropanoate;[BIS(T-BUTYLCARBONYLOXY)IODO] BENZENE
CAS:57357-20-7
MF:C16H23IO4
MW:406.26
EINECS:
Product Categories:
Mol File:57357-20-7.mol
BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97 Chemical Properties
Melting point 104-109 °C
form powder to crystal
color White to Light yellow
Safety Information
WGK Germany 3
MSDS Information
BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97 Usage And Synthesis
UsesRh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H AminationReagent for:
  • Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
  • Palladium-catalyzed diamination
  • Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
  • Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
  • C-H acyloxylation of arenes
  • Hypervalent iodine oxidant
BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97 Preparation Products And Raw materials
Raw materialsPivalic acid-->Iodobenzene-->(Diacetoxyiodo)benzene-->3,3-Dimethyl-2-oxobutyric acid

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