(-)-CAMPHENE

(-)-CAMPHENE
  • CAS No.:5794-04-7
Other grades of this product :
(-)-CAMPHENE Basic information
Product Name:(-)-CAMPHENE
Synonyms:2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane;2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan;L-Camphene;(1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE;Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-;(1R,4S)-3,3-Dimethyl-2-methylenebicyclo[2.2.1]heptane;(1S,4R)-2,2-Dimethyl-3-methylenenorbornane;[1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
CAS:5794-04-7
MF:C10H16
MW:136.23
EINECS:227-337-8
Product Categories:
Mol File:5794-04-7.mol
(-)-CAMPHENE Chemical Properties
Melting point 36-38 °C(lit.)
Boiling point 157.5-158.5 °C(lit.)
density 0.84 g/mL at 25 °C(lit.)
refractive index 1.4562 (estimate)
Fp 98 °F
Merck 14,1730
EPA Substance Registry SystemBicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1S,4R)- (5794-04-7)
Safety Information
Hazard Codes F
Risk Statements 11-10
Safety Statements 16-33-29
RIDADR UN 1325 4.1/PG 2
WGK Germany 3
RTECS EX1055000
HazardClass 4.1
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
(-)-CAMPHENE Usage And Synthesis
DefinitionChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has S configuration at position 1 and R configuration at position 4.
Purification MethodsPurify norbornane by fractionation through a Stedman column (see p. 11) at 100mm in a N2 atmosphere, crystallise it from EtOH and sublime it in a vacuum below its melting point. It is characterised by its camphenilone semicarbazone, m 217-218.5o, or camphor semicarbazone, m 236-238o. [NMR: Hana & Koch Chem Ber 111 2527 1978, Bartlett et al. Justus Liebigs Ann Chem 623 217 1959, Bain et al. J Am Chem Soc 72 3124 1950, Beilstein 5 IV 461.]
(-)-CAMPHENE Preparation Products And Raw materials

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