(1S)-(-)-CAMPHORSULFONYLIMINE

(1S)-(-)-CAMPHORSULFONYLIMINE
  • CAS No.:60886-80-8
Other grades of this product :
(1S)-(-)-CAMPHORSULFONYLIMINE Basic information
Product Name:(1S)-(-)-CAMPHORSULFONYLIMINE
Synonyms:(7S)-(-)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DEC-4-ENE 3,3-DIOXIDE;(7S)-10,10-DIMETHYL-3-THIA-4-AZATRICYCLO[5.2.1.01,5]DEC-4-ENE-3,3-DIOXIDE;(7S)-(-)-10,10-DIMETHYL-5-THIA-4-AZATRICYCLO[5.2.1.0(3,7)]DEC-3-ENE-5,5-DIOXIDE;(3AS)-(-)-4,5,6,7-TETRAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE 2,2-DIOXIDE;(3AS)-4,5,6,7-TETRAHYDRO-8,8-DIMETHYL-3H-3A,6-METHANO-2,1-BENZISOTHIAZOLE-2,2-DIOXIDE;(-)-10-CAMPHORSULFONIMINE;(1S)-(-)-CAMPHORSULFONYLIMINE;(1S)-(-)-(10-CAMPHORSULFONYL)IMINE
CAS:60886-80-8
MF:C10H15NO2S
MW:213.3
EINECS:
Product Categories:Sulfur & Selenium Compounds;Chiral Reagents;Bicyclic Monoterpenes;Biochemistry;Terpenes;Chiral Compound;Intermediates & Fine Chemicals;Pharmaceuticals
Mol File:60886-80-8.mol
(1S)-(-)-CAMPHORSULFONYLIMINE Chemical Properties
Melting point 228-230 °C (lit.)
Boiling point 337℃
density 1.50
refractive index -31 ° (C=2, CHCl3)
Fp 158℃
storage temp. Sealed in dry,Room Temperature
solubility Acetone, Dichloromethane, Hot Methanol
form Solid
pka-1.63±0.40(Predicted)
color White Cyrstalline
optical activity[α]19/D 34°, c = 1 in chloroform
BRN 85296
CAS DataBase Reference60886-80-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
(1S)-(-)-CAMPHORSULFONYLIMINE Usage And Synthesis
Chemical PropertiesWhite Cyrstalline Solid
UsesA useful synthetic intermediate. Used for asymmetric hydroxylation.
Uses(1S)-(-)-Camphorsulfonylimine is a useful synthetic intermediate. Used for asymmetric hydroxylation
(1S)-(-)-CAMPHORSULFONYLIMINE Preparation Products And Raw materials
Preparation Products(+)-(8,8-DICHLOROCAMPHORYLSULFONYL)OXAZIRIDINE

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