1,2-DIIODOETHANE

1,2-DIIODOETHANE
  • CAS No.:624-73-7
Other grades of this product :
1,2-DIIODOETHANE Basic information
Product Name:1,2-DIIODOETHANE
Synonyms:1,2-DIIODOETHANE;ETHYLENE DIIODIDE;ETHYLENE IODIDE;1,2-Diiodoethane,98%;Ethylenjodid;Glycoldiiodide;JACS-624-73-7;1,2-Diiodoethane ,98.5%
CAS:624-73-7
MF:C2H4I2
MW:281.86
EINECS:210-859-5
Product Categories:Alkyl;Building Blocks;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks
Mol File:624-73-7.mol
1,2-DIIODOETHANE Chemical Properties
Melting point 80-82 °C (lit.)
Boiling point 200.05°C
density 2.132 g/mL at 25 °C (lit.)
refractive index 1.8710
storage temp. 2-8°C
form Crystals or Crystalline Powder
Specific Gravity2.132
color Light brown to brown
Water Solubility Soluble in methanol. Insoluble in water.
Sensitive Air & Light Sensitive
BRN 1730870
Stability:Stable, but may discolour on exposure to light. Incompatible with strong bases, strong oxidizing agents.
CAS DataBase Reference624-73-7(CAS DataBase Reference)
EPA Substance Registry SystemEthane, 1,2-diiodo- (624-73-7)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
RIDADR 2811
WGK Germany 3
8-9-23
TSCA Yes
HazardClass 6.1(b)
PackingGroup III
HS Code 29033990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
1,2-DIIODOETHANE Usage And Synthesis
Chemical Propertiesdark brown crystals
Uses1,2-Diiodoethane is used as C-X bond formation reagent. It is also used as Pharmaceutical intermediates.
Uses1,2-Diiodoethane can be used:
  • To synthesize samarium(II) iodide-water complex (SmI2-H2O complex), a single-electron transfer reagent, to further synthesize 3-hydroxy carboxylic acids.
  • To synthesize derivatives of regioselective homopropargyl alcohols by using sonochemical Barbier-type reaction conditions.
  • As an iodine source and an effective reagent for the dehydroxy-iodination of alcohols.
Purification MethodsDissolve it in ether, wash it with saturated aqueous Na2S2O3, dry over MgSO4 and evaporate the ether in vacuo and distil it. Store it in the dark. [Molander et al. J Am Chem Soc 109 453 1987]. [Beilstein 1 IV 169.]

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