1-NITROBUTANE

1-NITROBUTANE
  • CAS No.:627-05-4
Other grades of this product :
1-NITROBUTANE Basic information
Product Name:1-NITROBUTANE
Synonyms:1-Nitrobutan;1-nitro-butan;Butane,1-nitro-;n-C4H9NO2;Nitro-butane
CAS:627-05-4
MF:C4H9NO2
MW:103.12
EINECS:210-980-3
Product Categories:Miscellaneous;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks;Building Blocks;Chemical Synthesis;Nitro Compounds;Nitrogen Compounds;Organic Building Blocks
Mol File:627-05-4.mol
1-NITROBUTANE Chemical Properties
Melting point -81 °C (lit.)
Boiling point 152-153 °C (lit.)
density 0.973 g/mL at 25 °C (lit.)
refractive index n20/D 1.410(lit.)
Fp 44 °C
pka8.69±0.29(Predicted)
Water Solubility 3.609g/L(25 ºC)
BRN 1743017
EPA Substance Registry System1-Nitrobutane (627-05-4)
Safety Information
Risk Statements 10
RIDADR UN 1993 3/PG 3
WGK Germany 3
RTECS EK5075000
HazardClass 3.2
PackingGroup III
HS Code 29042090
MSDS Information
ProviderLanguage
SigmaAldrich English
1-NITROBUTANE Usage And Synthesis
Uses1-Nitrobutane is used in method for preparing amine by reducing nitro compound with pinacolborane under catalysis of cyclic (alkyl) (amino) carbene chromium complex.
General DescriptionColorless liquid.
Air & Water ReactionsHighly flammable. Slightly water soluble .
Reactivity ProfileNitroalkanes, such as 1-NITROBUTANE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive. Nitroalkanes are insoluble in water. Flammable/combustible material. May be ignited by heat, sparks or flames.
1-NITROBUTANE Preparation Products And Raw materials
Raw materialsTRANS-4-OCTENE-->Butyraldehyde oxime-->n-Butane-->1-Chlorobutane-->Butylamine-->Butyric Acid-->Butylmagnesium chloride-->1-Bromobutane-->1-Iodobutane
Preparation ProductsBUTYLAMINE HYDROCHLORIDE-->1-Butyl nitrite

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